温州大学化学与材料工程学院

网站首页考博网温州大学ENGLISH

师资力量

夏远志

发布时间:2014-11-13 来源: 编辑: 点击[点击关闭]

个人简介
夏远志,博士,教授,硕士生导师。院长助理,化学系主任。
2004年6月毕业于湖北大学化学专业,获理学学士学位,同年9月考入中国科学院青海盐湖研究所攻读博士学位。期间,在北京大学余志祥教授和苏州大学李亚红教授的指导下从事物理有机化学和金属有机化学的研究工作;2009年6月获中国科学院研究生院理学博士学位。2009年7月加入温州大学化学与材料工程学院,先后担任讲师 、副教授、教授,从事 《有机化学》、 《高等有机化学》、《有机化学实验》、《化学专业英语》等课程的教学工作和物理有机化学、金属有机化学等方面的科研工作。2012年到2013年期间北京大学访问学者(合作导师:余志祥教授),2013年到2014年是德国弗莱堡大学访问学者(合作导师:Bernhard Breit教授)。目前已在J. Am. Chem. Soc.,J. Org. Chem., Org. Lett.,Chem. Eur. J.等国际著名期刊上发表研究论文近50篇。应邀为J. Am.  Chem. Soc., Chem. Sci., Chem. Eur. J.等国际杂志审稿。夏远志博士是第59届“林岛诺贝尔奖获得者大会”特邀“青年学者”;2009年获中国科学院“院长优秀奖”。
科研项目 1.国家自然科学基金: 过渡金属催化含氧化导向基团的芳基碳氢活化反应机理研究(21572163);
2.国家自然科学基金:有机反应中炔基金属卡宾中间体反应活性的理论与实验研究(21372178);
3.浙江省自然科学基金:过渡金属催化邻炔基苯基衍生物环化反应的机理研究及新合成设计(LY13B020007);
4.国家自然科学基金:一系列镍催化的有机反应机理的理论研究(21002073)(已结题);
5.温州市科技计划:氟尿嘧啶氨基酸类化合物的计算机辅助设计合成及抗肿瘤活性(Y20100003)(已结题)。
研究方向 1. 物理有机化学:通过理论计算、实验等手段研究有机反应的机理;
2. 有机合成化学:发展新的催化体系和绿色有机合成方法。
代表性论文

发表成果(*通讯作者):
(47) Tingjie You, Zhenrong Wang, Jiajia Chen, Yuanzhi Xia*, J. Org. Chem. 2017, 82, 1340. (影响因子: 4.72,;全文链接:http://pubs.acs.org/doi/abs/10.1021/acs.joc.6b02222)

(46) Jiajia Chen, Wei Guo, Zhenrong Wang, Lin Hu, Fan Chen*, Yuanzhi Xia*, J. Org. Chem. 2016, 81, 5504.(影响因子:4.72;全文链接:http://pubs.acs.org/doi/abs/10.1021/acs.joc.6b00844)

(45) Jiajia Chen, Wei Guo, Yuanzhi Xia*, J. Org. Chem. 2016, 81, 2635.(影响因子:4.72;全文链接:http://pubs.acs.org/doi/abs/10.1021/acs.joc.6b00003)

(44) Rajdip Karmakar, Phani Mamidipalli, Ryan M. Salzman, Seongwon Hong, Sang Young Yun, Wei Guo, Yuanzhi Xia*, Daesung Lee*, Org. Lett. 2016, 18, 3530. (影响因子:6.73;全文链接:
http://pubs.acs.org/doi/abs/10.1021/acs.orglett.6b01443) 

(43)Venkata R. Sabbasani, Hyunjin Lee, Yuanzhi Xia*, Daesung Lee*, Angew. Chem. Int. Ed. 2016, 55, 1151.(影响因子:11.26;全文链接:http://onlinelibrary.wiley.com/doi/10.1002/anie.201510006/abstract)

(42) Matthew J. O’Connor, Huaqing Liu , Daesung Lee*, Tao Zhou, Yuanzhi Xia*, Molecules 2015, 20, 21433.(影响因子:2.42;全文链接:http://www.mdpi.com/1420-3049/20/12/19783)

(41) Venkata R. Sabbasani, Genping Huang, Yuanzhi Xia*, Daesung Lee*, Chem. Eur. J. 2015, 21,17210. (影响因子:5.73;全文链接:http://onlinelibrary.wiley.com/doi/10.1002/chem.201503243/abstract)

(40) Pan Gao, Wei, Guo, Jingjing Xue, Yue Zhao, Yu Yuan, Yuanzhi Xia*, Zhuangzhi Shi*, J. Am. Chem. Soc. 2015, 137, 12231.
(影响因子:12.11 全文链接: http://pubs.acs.org/doi/abs/10.1021/jacs.5b06758

(39) Yanhua Mi, Tao Zhou, Kung-Pern Wang, Daesung Lee*, Yuanzhi Xia*, Chem. Eur. J. 2015, 21, 17256. (Hot Paper, 封面文章,影响因子:5.73;全文链接:http://onlinelibrary.wiley.com/doi/10.1002/chem.201502469/abstract)

(38) R. Karmakar, S. Ghorai, Yuanzhi Xia, Daesung Lee*, Molecules 2015, 20, 15862. (影响因子:2.42;全文链接:http://www.mdpi.com/1420-3049/20/9/15862)

(37)Wei Guo, Yuanzhi Xia*, J. Org. Chem. 2015, 80, 8113. (影响因子:4.72;全文链接:http://pubs.acs.org/doi/abs/10.1021/acs.joc.5b01201)

(36) Wei Guo, Tao Zhou, Yuanzhi Xia*, Organometallics, 2015, 34, 3012. (影响因子:4.12;全文链接:http://pubs.acs.org/doi/abs/10.1021/acs.organomet.5b00317)

(35) Tao Zhou, Wei Guo, Yuanzhi Xia*, Chem. Eur. J. 2015, 21, 9209.(影响因子:5.73;全文链接:http://onlinelibrary.wiley.com/doi/10.1002/chem.201500558/abstract)

(34) R. Karmakar, S. Y. Yun, Jiajia Chen, Yuanzhi Xia*, and Daesung Lee*, Angew. Chem. Int. Ed. 2015, 54, 6582. (影响因子:11.26;全文链接:http://onlinelibrary.wiley.com/doi/10.1002/anie.201412468/abstract)

(33) Genping Huang, Yuanzhi Xia*, ACS Catal. 2015, 5, 859.(影响因子:9.312;全文链接:http://pubs.acs.org/doi/abs/10.1021/cs501738p)

(32) Wei Guo, Yuanzhi Xia*, Synthesis 2014, 46, 2149.(Inivted contribution; 影响因子:2.500;全文链接:https://www.thieme-connect.com/products/ejournals/abstract/10.1055/s-0034-1378281

(31) Ming-Bo Zhou, Rui Pi, Ming Hu, Yuan Yang, Ren-Jie Song, Yuanzhi Xia*, and Jin-Heng Li*, Angew. Chem. Int. Ed. 2014, 53, 11338.(影响因子:11.336;全文链接:http://onlinelibrary.wiley.com/doi/10.1002/anie.201407175/abstract

(30) Yi Wang, Wei Liao, Genping Huang, Yuanzhi Xia, Zhi-Xiang Yu*, J. Org. Chem. 2014, 79, 5684.(影响因子:4.638;全文链接:http://pubs.acs.org/doi/abs/10.1021/jo500839c

(29) Tao Zhou, Yuanzhi Xia*, Organometallics, 2014, 33, 4230.(影响因子:4.253;全文链接:http://pubs.acs.org/doi/abs/10.1021/om500499s) 

(28) Nam-Kyu Lee, Sang Young Yun, Phani Mamidipalli, Ryan M. Salzman, Daesung Lee*, Tao Zhou, and Yuanzhi Xia*, J. Am. Chem. Soc. 2014, 136, 4363.
(影响因子:10.677 全文链接: http://pubs.acs.org/doi/abs/10.1021/ja500292x

(27) Phani Mamidipalli, Sang Young Yun, Kung-Pern Wang, Tao Zhou, Yuanzhi Xia*, and Daesung Lee*, Chem. Sci. 2014, 5, 2362.
(影响因子:8.314; 全文链接:http://pubs.rsc.org/en/Content/ArticleLanding/2014/SC/C3SC53478B

(26) Tao Zhou, Liang Xu, and Yuanzhi Xia*, Org. Lett. 2013, 15, 6074.
(影响因子:6.142; 全文链接:http://pubs.acs.org/doi/abs/10.1021/ol4029644)

(25) Venkata R. Sabbasani, Phani Mamidipalli, Huijie Lu, Yuanzhi Xia, and Daesung Lee*, Org. Lett. 2013, 15, 1552.
(影响因子:6.142; 全文链接:http://pubs.acs.org/doi/abs/10.1021/ol400331r)

(24) Genping Huang, Yuanzhi Xia*, Chunrui Sun, Jingwei Li, and Daesung Lee*, “Theoretical Studies on the Mechanism of the C–H Amination of Silyl Cyclopropenes by Azodicarboxylates”. J. Org. Chem. 2013, 78, 988.(影响因子:4.450;全文链接:http://pubs.acs.org/doi/abs/10.1021/jo302466z

(23) Chunrui Sun, Jingwei Li, Daesung Lee*, Genping Huang and Yuanzhi Xia*, “Formal C–H Amination of Cyclopropenes”. Chem. Commun. 2012, 48, 10990?10992(影响因子:6.169; 全文链接:http://pubs.rsc.org/en/content/articlelanding/2012/cc/c2cc35329f

(22) Ji-Cheng Wu, Lu-Bing Gong, Yuanzhi Xia, Ren-Jie Song, Ye-Xiang Xie, Jin-Heng Li* “Nickel-Catalyzed Kumada Reaction of Tosylalkanes with Grignard Reagents to Produce Alkenes and Modified Arylketones”. Angew. Chem. Int. Ed. 2012, 51, 9909.(影响因子:12.73;链接:http://onlinelibrary.wiley.com/doi/10.1002/anie.201205969/abstract

(21) Bo-Xiao Tang, Yue-Hua Zhang, Ren-Jie Song, Dong-Jun Tang, Guo-Bo Deng, Zhi-Qiang Wang, Ye-Xiang Xie, Yuan-Zhi Xia, and Jin-Heng Li*, “Intramolecular ipso-Halocyclization of 4-(p-Unsubstituted-aryl)-1-alkynes Leading to Spiro[4,5]trienones: Scope, Application, and Mechanistic Investigations”. J. Org. Chem. 2012, 77, 2837.
(影响因子:4.450;全文链接http://pubs.acs.org/doi/abs/10.1021/jo300037n

(20) Zhou Chen, Jian Wu, Yanmei Chen, Lei Li, Yuanzhi Xia*, Yahong Li*, Wei Liu, Tao Lei, Lijuan Yang, Dandan Gao, and Wu Li. “Rapid Accesses to Substituted Piperazines via Ti(NMe2)4-Mediated C-C Bond-Making Reactions”. Organometallics 2012, 31, 6005?6013.
(影响因子:3.963;全文链接:http://pubs.acs.org/doi/abs/10.1021/om300022u

(19) Genping Huang, Kelei Xie, Daesung Lee, Yuanzhi Xia*.“Reactivity of Alkynyl Metal-Carbenoids: DFT Study on the Pt-Catalyzed Cyclopropanation of Propargyl Ester-containing 1,3-Diynes”. Org. Lett. 2012, 14, 3850.(影响因子:5.862;全文链接:http://pubs.acs.org/doi/abs/10.1021/ol301497v

(18) Bing Cheng, Genping Huang, Liang Xu, Yuanzhi Xia*. “Mechanism of the N-Protecting Group Dependent Annulations of 3-Aryloxy Alkynyl Indoles under Gold Catalysis: A Computational Study”. Org. Biomol. Chem. 2012, 10, 4417.(影响因子:3.696;全文链接:pubs.rsc.org/en/content/articlehtml/2012/ob/c2ob25316j)

(17) Liang Xu, Qi Zhu, Genping Huang, Bing Cheng, Yuanzhi Xia*. “Computational Elucidation of the Internal Oxidant-Controlled Reaction Pathways in Rh(III)-Catalyzed Aromatic C-H Functionalization”. J. Org. Chem. 2012, 77, 3017. (Featured article, 封面文章).
(影响因子:4.450;全文链接http://pubs.acs.org/doi/abs/10.1021/jo202431q 封面链接:http://pubs.acs.org/action/showLargeCover?issue=362713648

(16) Gengping Huang, Bing Cheng, Liang Xu, Yahong Li*, Yuanzhi Xia*. “Mechanism of the Transition Metal-Catalyzed Hydroarylation of Bromo-Alkyne Revisited: Hydrogen versus Bromine Migration”. Chem. Eur. J. 2012, 18, 5401. (影响因子:5.925;全文链接:http://onlinelibrary.wiley.com/doi/10.1002/chem.201102692/abstract

(15) Yuanzhi Xia*, Genping Huang. “Mechanisms of the Au- and Pt-Catalyzed Intramolecular Acetylenic Schmidt Reactions: A DFT Study”.J. Org. Chem. 2010, 75, 7842.(影响因子:4.450;全文链接:http://pubs.acs.org/doi/abs/10.1021/jo202431q

(以下为研究生期间的主要成果,导师:余志祥教授和李亚红教授)
(14) Yuanzhi Xia, Alexander S. Dudnik, Yahong Li*, Vladimir Gevorgyan*. “On the Validity of Au-vinylidenes in the Gold-Catalyzed 1,2-Migratory Cycloisomerization of Skipped Propargylpyridines”. Org. Lett. 2010, 12, 5538?5541. (影响因子:5.862;全文链接:http://pubs.acs.org/doi/abs/10.1021/ol1024794

(13) Yuanzhi Xia, A. S. Dudnik, V. Gevorgyan, Yahong Li* “Mechanistic Insighs into the Gold-Catalyzed Cycloisomerization of Bromoallenyl Ketones: Ligand-Controlled Regioselectivity”. J. Am. Chem. Soc. 2008, 130, 6940?6941.(影响因子:9.907;全文链接:http://pubs.acs.org/doi/abs/10.1021/ja802144t

(12) Yuanzhi Xia, Yong Liang, Yuanyuan Chen, Ming Wang, Lei Jiao, Feng Huang, Song Liu, Yahong Li, Zhi-Xiang Yu* “An Unexpected Role of a Trace Amount of Water in Catalyzing Proton Transfer in Phosphine Catalyzed (3 + 2) Cycloaddition of Allenoates and Alkenes”. J. Am. Chem. Soc. 2007, 129, 3470?3471. (影响因子:9.907;全文链接:http://pubs.acs.org/doi/abs/10.1021/ja068215h

(11) Yuanzhi Xia, Yahong Li*, Wu Li “Theoretical Study on the Consecutive 1,2-Hydroboration and 1,1-Organoboration Reactions of Alkyn-1-yl(vinyl)silanes with Borane”. J. Organomet. Chem. 2008, 693, 3722?3728.
(影响因子:2.384;全文链接:http://www.sciencedirect.com/science/article/pii/S0022328X08005524)

(10) Yuanzhi Xia, Fengying Zhou, Yahong Li*, Wu Li. “Effect of Electron-withdrawing group on the [3,3]-Sigmatropic Rearrangements of 1,5-Enynes, 1,5-Diynes and 1,2-Diene-5-ynes: A Theoretical Study”.J. Mol. Struct. (THEOCHEM ) 2009, 904, 69?73.
(影响因子:1.22;全文链接:http://www.sciencedirect.com/science/article/pii/S0166128009001407)

(9) Alexander S. Dudnik, Yuanzhi Xia, Yahong Li*, Vladimir Gevorgyan*.“Computation-Guided Development of Au-Catalyzed Cycloisomerizations Proceeding via 1,2-Si or 1,2-H Migrations: Regiodivergent Synthesis of Silylfurans”. J. Am. Chem. Soc. 2010, 132, 7645?7655.
(影响因子:9.907;全文链接:http://pubs.acs.org/doi/abs/10.1021/ja910290c)

(8) Genping Huang, Yuanzhi Xia, Yahong Li. “Substituent Effects on the Tautomerism of Monochalcogenocarboxylic Acids XC(O)YH (X=H, F, NH2, OH, CN, and CH3; Y=S, Se, and Te): A Theoretical Study”. J. Mol. Struct. (THEOCHEM ) 2009, 896, 80?84.
(影响因子:1.22;全文链接:http://www.sciencedirect.com/science/article/pii/S0166128008006738)

(7) Wei Ren, Yuanzhi Xia, Shun-Jun Ji, Yong Zhang, Xiaobing Wan*, Jing Zhao. “Wacker-Type Oxidation of Alkynes into 1,2-Diketones Using Molecular Oxygen”. Org. Lett. 2009, 11, 1841?1844.
(影响因子:5.862;全文链接:http://pubs.acs.org/doi/abs/10.1021/ol900344g)

(6) Yong Liang, Song Liu, Yuanzhi Xia, Yahong Li, Zhi-Xiang Yu*. “Mechanism, Regioselectivity, and the Kinetics of Phosphine-Catalyzed [3+2] Cycloaddition Reactions of Allenoates and Electron-deficient Alkenes”. Chem. Eur. J. 2008, 14, 4361?4373.
(影响因子:5.925;全文链接:http://onlinelibrary.wiley.com/doi/10.1002/chem.200701725/abstract)

(5) Xiaojuan Cheng, Yuanzhi Xia, Hua Wei, Bin Xu, Chongguang Zhang, Yahong Li*, Guimin Qian, Xiaohua Zhang, Kai Li, Wu Li. “Lewis Acid Catalyzed Intermolecular Olefin Hydroamination: Scope, Limitation, and Mechanism”. Eur. J. Org. Chem. 2008, 1929?1936.(影响因子:3.21;全文链接:http://onlinelibrary.wiley.com/doi/10.1002/ejoc.200701080/abstract)

(4) Jing-Wen Ran, Su-Yun Zhang, Bin Xu, Yuanzhi Xia, Dong Guo, Jing-Yan Zhang, Yahong Li*. “Tetranuclear Nickel(II) Complex with Tripodal Hydroxyl Ligand Functionalized by Additional Salicylaldehyde Donor Pendant: Synthesis, Crystal Structure and Magnetic Property”. Inorg. Chem. Commun. 2008, 11, 73?76.(影响因子:2.205;全文链接:http://www.sciencedirect.com/science/article/pii/S1387700307003759)

(3) Fu-Qiang Shi, Xin Li, Yuanzhi Xia, Liming Zhang, Zhi-Xiang Yu* “DFT Study of the Mechanisms of In Water Au(I)-Catalyzed Tandem [3,3]-Rearrangement/Nazarov Reaction/[1,2]-Hydrogen Shift of Enynyl Acetates: A Proton-Transport Catalysis Strategy in the Water-Catalyzed [1,2]-Hydrogen Shift” J. Am. Chem. Soc. 2007, 129, 15503?15512.
(影响因子:9.907 全文链接:http://pubs.acs.org/doi/abs/10.1021/ja071070%2B)

(2) Hua Wei, Guimin Qian, Yuanzhi Xia, Kai Li, Yahong Li*, Wu Li. “BiCl3-Catalyzed Hydroamination of Norbornene with Aromatic Amines”. Eur. J. Org. Chem. 2007, 4471?4474.(影响因子:3.21;全文链接:http://onlinelibrary.wiley.com/doi/10.1002/ejoc.200700483/abstract)

(1) Abraham F. Jalbout,* Bartosz Trzaskowski,* Yuanzhi Xia, Yahong Li. “Geometry Predictions, Vibrational Analysis and IR Intensities of XH3Y (X=C, Si, Ge, Y=F, Cl, Br) Calculated by Hybrid Density Functional Theory, MP2 and MP4 Methods” Acta Chim. Slov. 2007, 54, 769?777. (影响因子:1.093;全文链接:http://acta.chem-soc.si/54/54-4-769.pdf)
 

联系方式 电子邮箱:xyz@wzu.edu.cn
通信地址:浙江省温州市茶山高教园区温州大学化学与材料工程学院,邮编:325035
本课题组欢迎热爱有机化学和金属有机化学研究的研究生、本科生加盟!
课题组成员

当前成员:
Adebesin Hassan Omoniyi, 2016级硕士留学生,研究方向:有机合成

Dr. J. Kuang, 博士后研究员,研究方向:有机合成
陈英英:2016级硕士生(合作培养),研究方向:有机合成
杨安:2016级硕士生,研究方向:有机合成
林波:2016级硕士生,研究方向:有机合成
林永佳:2016级硕士生,研究方向:物理有机化学
谢培培:2015级硕士生,研究方向:物理有机化学

贾萌萌:2015级硕士生,研究方向:有机合成化学

王振荣:2014级硕士生,研究方向:有机合成化学

尤婷杰:2014级硕士生,研究方向:有机合成化学

已毕业成员:
郭威:2013级有机化学硕士生,主要从事物理有机化学及有机合成研究(毕业去向:山东某外企)。
陈佳佳:2013级有机化学硕士生,主要从事物理有机化学及有机合成研究(毕业去向:北京某企业)。
周涛:2012级有机化学硕士生,毕业去向:上海某企业。
米艳华:2010级有机化学硕士生,毕业去向:某省级重点中学化学教师。
徐亮:2009级机化学硕士生,毕业去向:西安交通大学博士生,从事有机合成研究。2016起石河子大学任教。
程兵:2009级机化学硕士生,毕业去向:中国科学院化学研究所研究助理,从事有机及高分子材料合成研究。
黄跟平:2009-2011年联合培养研究生,毕业去向:瑞典斯德哥尔摩大学博士后。20151月起任天津大学副教授。
张文军:2009-2011年联合培养研究生,毕业去向:广西知识产权局公务员。

(更新时间:2017年3月)