温州大学化学与材料工程学院

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徐 清

发布时间:2016-11-29 来源: 编辑: 点击[点击关闭]




 

徐清,男,汉族,197711月出生,浙江永康人,中共党员、教授、博士、硕士研究生导师,中国化学会会员。19996月毕业于浙江大学化学系,获理学学士学位;同年保送浙江大学硕博连读研究生,20046月获理学博士学位(导师:黄宪院士);200410月赴日本产业技术综合研究所(National Institute of Advanced Industrial Science and Technology, AIST),作为特别研究员从事手性有机膦化合物合成与应用研究(合作导师:Li-Biao Han教授);20092月进入温州大学化学与材料工程学院从事教学科研工作;201212月破格晋升教授职称;20153--9月美国威斯康辛大学麦迪逊分校(University of Wisconsin-Madison)访问学者(合作教授:Shannon Stahl)。2014年获浙江省杰出青年基金,入选2016年江苏省企业双创人才、浙江省151人才工程第二层次、浙江省高校优秀青年教师、温州市551人才工程第一层次、温州市“580海外精英引进计划温州市特聘专家、第十三届温州市十大杰出青年2015年淮安市淮上英才计划 创新创业领军人才,温州市青年联合会第八届委员会委员、温州大学青年博士联谊会副会长、温州大学首届学生科技创新十佳指导教师。研究方向为绿色化学和绿色合成研究、过渡金属催化反应研究、高选择元素有机化合物合成应用研究、不对称催化与合成研究,以及相关新反应机理研究。在醇活化应用领域发展了多种醇活化新策略、在世界上首次提出“接力”方法学及其机理,提升了醇活化理论、促进拓展了绿色的醇类化合物在医药农药等中间体中的合成应用,获国内外同行专家广泛认可。至今已在J. Am. Chem. Soc.Angew. Chem.Green Chem.Chem. Commun.Org. Lett.Chem. Eur. J.Adv. Synth. Catal.Top. Curr. ChemJ. Org. Chem.Catal. Sci. Technol.Org. Biomol. Chem.Mini-Rev. Med. Chem.RSC Adv.TetrahedronCatal. Lett.Synlett.Tetrahedron Lett.J. Organometallic Chem.等国际SCI学术期刊发表六十多篇学术论文申请二十多项国内外发明专利、已获授权十五项多篇论文被选为杂志封面论文、杂志年度优秀论文、浙江省基金优秀论文、温州市自然科学优秀论文或被ScienceChem. Rev.J. Am. Chem. Soc.Angew. Chem.Green. Chem.等系列权威期刊重点引用或评价,或被Advances in EngineeringSynfactsOrganic Chemistry PortalLabome Org.作为亮点收录介绍,或被研究同行和《化学工业日报》高度评价研究成果获浙江省高校优秀科研成果奖、浙江省自然科学学术奖等。十多次受邀在国内高校研究所和国际国内学术会议上作学术报告,国家自然科学基金和浙江省自然科学基金评审专家、Advances in Engineering顾问,受邀为Nature Chem.J. Am. Chem. Soc.Chem. Sci.ACS Catal.Green Chem.Chem. Commun.Org. Lett.Adv. Synth. Catal.Chem.-Eur. J.Catal. Sci. Technol.ChemCatChemInorg. Chem.Top. Curr. Chem.Org. Chem. Front.J. Org. Chem.Dalt. Trans.Org. Biomol. Chem.RSC AdvancesCurr. Org. Chem.Curr. Green. Chem.Min-Rev. Med. Chem.Min-Rev. Org. Chem.J. Mol. Catal. A: Chem.Tetrahedron AsymmetryTetrahedron Lett.Beil. J. Org. Chem.New J. Chem.Lett. Org. Chem.Catal. Lett.SynlettSynthesisChem. Lett.Chin. J. CatalPSSiChin. J. Chem.Chin. J. Org. Chem.等国际SCI杂志审稿。




(1)   Jianhui Chen,† Yang Li,† Shuangyan Li, Jianping Liu,* Fei Zheng, Zhengping Zhang, and Qing Xu*, Aldehyde/Ketone-Catalyzed Highly Selective Synthesis of 9-Monoalkylated Fluorenes by Dehydrative C-Alkylation with Primary and Secondary Alcohols, Green Chem. 2016, DOI: 10.1039/c6gc02518h (IF 8.506)

(2)   Xiang Ren, Qihang Guo, Jianhui Chen, Hujun Xie,* Qing Xu* and Zhan Lu*. Visible-Light Promoted Distereodivergent Intramolecular Oxyamidation of Alkenes. Chem. Eur. J. 2016, DOI: 10.1002/chem.201603977 (SCI-II, IF: 5.731)

(3)   Xiaokai Cheng, Bo Yang, Xingen Hu, Qing Xu, and Zhan Lu,* Visible-Light-Promoted Metal-Free Aerobic Oxidation of Primary Amines to Acids and Lactones. Chem. Eur. J. 2016, DOI: 10.1002/chem.201604440 (SCI-II, IF: 5.731)

(4)   Yang Li, Haonan Chen, Jianping Liu,* Xujun Wan, and Qing Xu*, Clean Synthesis of Primary to Tertiary Carboxamides by CsOH-Catalyzed Aminolysis of Nitriles in Water, Green Chem. 2016, 18 (18), 4865–4870. (SCI-II, IF 8.506)

DOI: 10.1039/C6GC01565D

(5)  

(6)   Wang, Wei-Min; Liu, Li-Juan; Yao, Lan; Meng, Fan-Jie; Sun, Yong-Ming; Zhao, Chang-Qiu; Xu, Qing; Han, Li-Biao. Stereospecific Preparations of P-Stereogenic Phosphonothioates and Phosphonoselenoates. J. Org. Chem. 2016, 81 (15), 6843-6847. (SCI-IIIF: 4.721)

DOI: 10.1021/acs.joc.6b01192

(7)   Jianping Liu,* Chao Wang, Xiantao Ma, Xinkang Shi, Xin Wang, Huan Li, and Qing Xu.* Simple Synthesis of Benzazoles by Substrate-Promoted CuI-Catalyzed Aerobic Oxidative Cyclocondensation of o-Thio/Amino/Hydroxyanilines and Amines under Air. Catal. Lett. 2016, 146 (10), 2139-2148 (SCI-III, IF 2.294)

DOI: 10.1007/s10562-016-1818-2

(8)   Qing Xu,* Huamei Xie, Er-Lei Zhang, Xiantao Ma, Jianhui Chen, Xiao-Chun Yu, and Huan Li. Selective Catalytic Hoffmann N-Alkylation of Poor Nucleophilic Amines and Amides with Catalytic Amounts of Alkyl Halides. Green. Chem. 2016, 18 (14), 3940-3944. (SCI-II, IF: 8.506).

DOI: 10.1039/C6GC00938G

(9)   Xiantao Ma, Quan Liu, Xiaojuan Jia, Chenliang Su* and Qing Xu*, Efficient Synthesis of Unsymmetrical Heteroaryl Thioethers and Chalcogenides by Alkali Hydroxide-Mediated SNAr Reactions of Heteroaryl Halides and Dichalcogenides, RSC Adv. 2016, 6 (62), 56930-56935. (IF 3.84).

DOI: 10.1039/C6RA10517C

(10) Xiantao Ma, Chenliang Su, Qing Xu*, N-Alkylation by hydrogen autotransfer reactions (Invited Review) in Hydorgen Transfer Reactions (Eds.: Guillena, G.; Ramón, D. J.), Top. Curr. Chem. 2016, 374:27, 1-74. (IF 4.464).

DOI: 10.1007/s41061-016-0027-1

(11) Qiang Li, Tieqiao Chen, Qing Xu,* Li-Biao Han.* Rhodium- and Iridium-Catalyzed Asymmetric Addition of Optically Pure P-Chiral H-Phosphinates to Aldehydes Leading to Optically Active α-Hydroxyphosphinates. Chem. Eur. J. 2016, 22 (18), 6213-6217. (SCI-II, IF: 5.731)

DOI:dx.doi.org/10.1002/chem.201600115

Highlighted by Synfacts: Synfacts 2016, 12(7), 0710

(12) Xiaohui Li, Shuangyan Li, Qiang Li, Xu Dong, Yang Li, Xiaochun Yu, Qing Xu.* Efficient and Practical Catalyst-Free-Like Dehydrative N-Alkylation of Amines and Sulfinamides with Alcohols Initiated by Aerobic Oxidation of Alcohols under Air. Tetrahedron 2016, 72 (2), 264-272 (SCI-III, IF: 2.641).

DOI: 10.1016/j.tet.2015.11.016.

(13) Lei Yu,* Yaping Huang, Zheng Wei, Yuanhua Ding, Chenliang Su,* Qing Xu.* Heck Reactions Catalyzed by Ultrasmall and Uniform Pd Nanoparticles Supported on Polyaniline. J. Org. Chem. 2015, 80 (17), 8677–8683 (SCI-IIIF: 4.721).

DOI: 10.1021/acs.joc.5b01358

X-MOL化学咨询平台亮点摘录http://www.x-mol.com/news/1350

(14) Lei Yu,* Jianqing Ye, Xu Zhang, Yuanhua Ding, Qing Xu.* Recyclable (PhSe)2-catalyzed selective oxidation of isatin by H2O2: a practical and waste-free access to isatoic anhydride under mild and neutral conditions. Catal. Sci. Technol. 2015, 5 (10), 4830-4838 (SCI-II, IF: 5.426).

DOI: 10.1039/C5CY01030F

Graphical abstract: Recyclable (PhSe)2-catalyzed selective oxidation of isatin by H2O2: a practical and waste-free access to isatoic anhydride under mild and neutral conditions

(15) Lei Yu,* Mingxuan Liu, Fenglin Chen and Qing Xu.* Heterocycles from Methylenecyclopropanes, Org. Biomol. Chem. 2015, 13, 8379-8392 (SCI-III, IF: 3.562, 封面论文).

DOI: 10.1039/C5OB00868A.

(16) Xinkang Shi, Junmei Guo, Jianping Liu, Mingde Ye, Qing Xu.* Unexpectedly Simple Synthesis of Benzazoles by t-BuONa-Catalyzed Direct Aerobic Oxidative Cyclocondensation of o-Thio/Hydroxy/Aminoanilines with Alcohols under Air. Chem. Eur. J. 2015, 21 (28), 9988-9993 (SCI-II, IF: 5.731).

DOI: 10.1002/chem.201501184

 Highlighted by Synfacts: Synfacts 2015, 11(9), 0925

Highlighted by Advances in Engineering as a Key Scientific Article contributing to excellence in engineering, scientific and industrial research

      

(17) Shuangyan Li, Xiaohui Li, Qiang Li, Qiaochao Yuan, Xinkang Shi, Qing Xu.* Structure-Dependent Tautomerization Induced Catalyst-Free Autocatalyzed N-Alkylation of Heteroaryl Amines with Alcohols. Green Chem. 2015, 17 (6), 3260-3265 (SCI-II, IF: 8.02).

   DOI:10.1039/C4GC02542C

(18) Qing Xu,* Huamei Xie,** Pingliang Chen,** Lei Yu, Jianhui Chen, Xingen Hu* (** These authors contribute equally to this work). Organohalides-Catalyzed Dehydrative O-Alkylation between Alcohols: A Facile Etherification Method for Aliphatic Ether Synthesis. Green Chem. 2015, 17 (5), 2774-2779 (SCI-II, IF: 8.02).

DOI:10.1039/C5GC00284B

X-MOL化学咨询平台亮点摘录:http://www.x-mol.com/news/1171

 

(19) Xu Zhang, Jianqing Ye, Lei Yu,* Xinkang Shi, Ming Zhang, Qing Xu,* Mark Lautens. Organoselenium-Catalyzed Baeyer-Villiger Oxidation of α,β-Unsaturated Ketones by Hydrogen Peroxide to Access Vinyl Esters. Adv. Synth. Catal. 2015, 357 (5), 955-960 (SCI-II, IF: 5.663).

   DOI: 10.1002/adsc.201400957

   Organic Chemistry Portal摘录http://www.organic-chemistry.org/Highlights/2016/14March.shtm

(20) Qiang Li, Yao Huang, Tieqiao Chen, Yongbo Zhou,* Qing Xu, Shuang-Feng Yin,* Li-Biao Han. Copper-Catalyzed Aerobic Oxidative Amination of sp3C–H Bonds: Efficient Synthesis of 2-Hetarylquinazolin-4(3H)-ones. Org. Lett. 2014, 16 (14), 3672–3675 (SCI-II, IF: 6.364).

   DOI:10.1021/ol501454j

(21) Lei Yu,* Jun Wang, Hongen Cao, Kehong Ding, Qing Xu*, A Review on Catalyzed Dimerization of Acrylonitrile, Chin. J. Org. Chem. 2014, 37 (7), 1986-1991 (SCI, IF: 0.917).

   DOI:10.6023/cjoc201405004

(22) Xiaojuan Jia, Lei Yu, Jianping Liu, Qing Xu,* Marcel Sickert, Lianhui Chen, and Mark Lautens.* Sulfur-silicon bond activation catalysed by Cl/Br ions: waste-free synthesis of unsymmetrical thioethers by replacing fluoride catalysis and fluorinated substrates in SNAr reactions, Green Chem. 2014, 16 (7), 3444-3449 (SCI-II, IF: 8.02).

   DOI: 10.1039/C4GC00535J

(23) Lei Yu,* Jun Wang, Xu Zhang, Hongen Cao, Genling Wang, Kehong Ding, Qing Xu*, Mark Lautens. Practical preparation of 2-methyleneglutaronitrile via an efficient and highly selective head-to-tail dimerization of acrylonitrile catalyzed by low-loading tricyclohexylphosphine. RSC Adv. 2014, 4 (37), 19122-19126 (SCI-III, IF: 3.84).

   DOI:10.1039/C4RA02810D

(24) Haonan Chen, Wujie Dai, Yi Chen, Qing Xu,* Jianhui Chen, Lei Yu, Yajuan Zhao, Mingde Ye, Yuanjiang Pan.* Efficient and selective nitrile hydration reaction in water catalyzed by unexpected dimethylsulfinyl anion generated in situ from CsOH and DMSO. Green Chem. 2014, 16 (4), 2136-2141 (SCI-II, IF: 8.02).

   DOI:10.1039/C3GC42310G

(25) Lei Yu,* Hongyan Li, Xu Zhang, Jianqing Ye, Jianping Liu, Qing Xu,* Mark Lautens. Organoselenium-Catalyzed Mild Dehydration of Aldoximes: An Unexpected Practical Method for Organonitrile Synthesis. Org. Lett. 2014, 15 (3), 1346-1349 (SCI-II, IF: 6.364).

DOI:10.1021/ol500075h

Organic Chemistry Portal摘录:http://www.organic-chemistry.org/abstracts/lit4/413.shtm

  

(26) Qing Xu,* Jianhui Chen, Haiwen Tian, Xueqin Yuan, Shuangyan Li, Chongkuan Zhou, Jianping Liu. Catalyst-Free Dehydrative α-Alkylation of Ketones with Alcohols: Green and Selective Autocatalyzed Synthesis of Alcohols and Ketones. Angew. Chem. 2014, 126 (1), 229-233; Angew. Chem. Int. Ed. 2014, 53 (1), 225-229 (SCI-I, IF: 13.734).

DOI:10.1002/ange.201308642; DOI:10.1002/anie.201308642

浙江省基金网站报道:http://www.zjnsf.gov.cn/h/01/news_view.aspx?appid=GUDD5EB45D5C95010591E580385CA982CF8

(27) Lei Yu,* Yulan Wu, Hongen Cao, Xu Zhang, Xinkang Shi, Jie Luan, Tian Chen, Yi Pan, Qing Xu.* Facile Synthesis of 2-Methylenecyclobutanones via Ca(OH)2-Catalyzed Direct Condensation of Cyclobutanone with Aldehydes and (PhSe)2-Catalyzed Baeyer-Villiger Oxidation to 4-Methylenebutanolides. Green Chem. 2014, 16 (1), 287-293 (SCI-II, IF: 8.02).

   DOI:10.1039/C3GC41562G

(28) Erlei Zhang, Haiwen Tian, Sendong Xu, XiaochunYu, Qing Xu.* Iron-Catalyzed Direct Synthesis of Imines from Amines or Alcohols and Amines via Aerobic Oxidative Reactions under Air. Org. Lett. 2013, 15 (11), 2704-2707 (SCI-II, IF: 6.364).

DOI:10.1021/ol4010118

Organic Chemistry Portal摘录:www.organic-chemistry.org/abstracts/lit4/049.shtm

   

(29) Quan Liu, Zhongxiang Lu, Wenfei Ren, Kaibo Shen, Yu Wang, Qing Xu.* Efficient Synthesis of Unsymmetrical Heteroaryl Ethers by a Transition Metal-Free C-O Cross-Coupling Reaction of Activated and Unactivated Heteroaryl Chlorides with Alcohols and Phenols. Chin. J Chem. 2013, 31 (6), 764-772 (SCI, IF: 0.917).

   DOI:10.1002/cjoc.201300120

(30) Bo Huang, Haiwen Tian, Shoushuai Lin, Meihua Xie, Xiaochun Yu,* Qing Xu.* Cu(I)/TEMPO-Catalyzed Aerobic Oxidative Synthesis of Imines Directly from Primary and Secondary Amines under Ambient and Neat Conditions. Tetrahedron Lett. 2013, 54 (22), 2861-2864 (SCI-III, IF: 2.379).

   DOI:10.1016/j.tetlet.2013.03.098

(31) Qing Xu,* Yong-Bo Zhou, Chang-Qiu Zhao, Shuang-Feng Yin, Li-Biao Han.* Transition Metal-Catalyzed Efficient and Green Transformations of P(O)−H Compounds to Functional Organophosphorus Compounds. Mini-Rev. Med. Chem. 2013, 13 (6), 824-835 (SCI-III, IF: 2.903).

DOI:10.2174/1389557511313060005

(32) Qing Xu,* Jianhui Chen, Quan Liu. Aldehyde-Catalyzed Transition Metal-Free Dehydrative β-Alkylation of Methyl Carbinols with Alcohols. Adv. Synth. Catal. 2013, 355 (4), 697-704 (SCI-II, IF: 5.663).

   DOI:10.1002/adsc.201200996

(33) Lei Yu,* Yulan Wu, Tian Chen, Yi Pan, Qing Xu.* Direct Synthesis of Methylene-1,2-dichalcogenolanes via Radical [3+2] Cycloaddition of Methylenecyclopropanes with Elemental Chalcogens. Org. Lett. 2013, 15 (1), 144-147 (SCI-II, IF: 6.364).

   DOI:10.1021/ol3031846

(34) Qing Xu,* Qiang Li, Xiaogang Zhu, Jianhui Chen. Green and Scalable Aldehyde-Catalyzed Transition Metal-Free Dehydrative N-Alkylation of Amides and Amines with Alcohols. Adv. Synth. Catal. 2013, 355 (1), 73-80 (SCI-II, IF: 5.663).

   DOI:10.1002/adsc.201200881

Organic Chemistry Portal摘录:http://www.organic-chemistry.org/Highlights/2013/28October.shtm

(35) Qing Xu,* Qiang Li. Recent Advances of Transition Metal-Catalyzed Aerobic Dehydrative Reactions of Alcohols and Amines and Related Reactions. Chin. J. Org. Chem. 2013, 33 (1), 18-35 (SCI, IF: 0.741).

   DOI:10.6023/cjoc201208016

(36) Haiwen Tian, Xiaochun Yu, Qiang Li, Jianxin Wang, Qing Xu.* General, Green, and Scalable Synthesis of Imines from Alcohols and Amines by a Mild and Efficient Copper-Catalyzed Aerobic Oxidative Reaction in Open Air at Room Temperature. Adv. Synth. Catal. 2012, 354 (14-15), 2671-2677 (SCI-II, IF: 5.663).

DOI:10.1002/adsc.201200574

 Cited and commented by Science-2013-339-43 as an exceptionally good method for imine preparation from alcohols and amines)

 

(37) Qing Xu, Chang-Qiu Zhao, Yong-Bo Zhou, Shuang-Feng Yin, Li-Biao Han.* Transition Metal-Catalyzed Transformations of P(O)-H Bonds. Chin. J. Org. Chem. 2012, 32 (10), 1761-1775 (SCI, IF: 0.741; 外封面论文).

   DOI:10.6023/cjoc201207024

(38) Xiaochun Yu, Lan Jiang, Qiang Li, Yuanyuan Xie, Qing Xu.* Palladium-Catalyzed N-Alkylation of Amides and Amines with Alcohols Employing the Aerobic Relay Race Methodology. Chin. J. Chem. 2012, 30 (10), 2322-2332 (SCI, IF: 0.917).

DOI:10.1002/cjoc.201200462

(39) Qiang Li, Songjian Fan, Qing Sun, Haiwen Tian, Xiaochun Yu, Qing Xu.* Copper-Catalyzed N-Alkylation of Amides and Amines with Alcohols Employing the Aerobic Relay Race Methodology. Org. Biomol. Chem. 2012, 10 (15), 2966-2972 (SCI-III, IF: 3.562).

DOI:10.1039/C1OB06743E

Highlighted by Org. Biomol. Chem. as Outside Front Cover.

Featured in the top 10% of the most highly cited articles published in the latest Impact Factor window 2011-2012

(40) Shiheng Liao, Kangkang Yu, Qiang Li, Haiwen Tian, Zhengping Zhang, Xiaochun Yu, Qing Xu.* Copper-Catalyzed C-Alkylation of Secondary Alcohols and Methyl Ketones with Alcohols Employing the Aerobic Relay Race Methodology. Org. Biomol. Chem. 2012, 10 (15), 2973-2978 (SCI-III, IF: 3.562).

DOI:10.1039/C1OB06739G

Highlighted by Org. Biomol. Chem. as Outside Front Cover.

Featured in the top 10% of the most highly cited articles published in the latest Impact Factor window 2011-2012

(41) Xiaochun Yu, Chuanzhi Liu, Lan Jiang, Qing Xu.* Manganese Dioxide Catalyzed N-Alkylation of Sulfonamides and Amines with Alcohols under Air. Org. Lett. 2011, 13 (23), 6184-6187 (SCI-II, IF: 6.364).

DOI:10.1021/ol202582c

Organic Chemistry Portal摘录: http://www.organic-chemistry.org/abstracts/lit3/476.shtm

(42) Lan Jiang, Luolu Jin, Haiwen Tian, Xueqin Yuan, Xiaochun Yu,* Qing Xu.* Direct and Mild Palladium-Catalyzed Aerobic Oxidative Synthesis of Imines from Alcohols and Amines under Ambient Conditions. Chem. Commun. 2011, 47 (38), 10833-10835 (SCI-II, IF: 6.834).

DOI:10.1039/c1cc14242a

十一五浙江省自然科学基金优秀论文浙江省自然科学学术奖三等奖

(43) Chuanzhi Liu, Shiheng Liao, Qiang Li, Sunlin Feng, Qing Sun, Xiaochun Yu,* Qing Xu.* Discovery and Mechanistic Studies of a General Air-Promoted Metal-Catalyzed Aerobic N-Alkylation Reaction of Amides and Amines with Alcohols. J. Org. Chem. 201176 (14), 5759-5773 (SCI-II, IF: 4.721).

DOI:10.1021/jo200862p

(44) Sun Lin Feng, Chuan Zhi Liu, Qiang Li; Xiao Chun Yu, Qing Xu.* Rhodium-Catalyzed Aerobic N-Alkylation of Sulfonamides with Benzylic Alcohols. Chin. Chem. Lett. 201122 (9), 1021-1024. (SCI, IF: 1.21)

 DOI:10.1016/j.cclet.2011.03.014

《中国化学快报》2011年度优秀论文、《中国化学快报》2013年度高被引论文

(45) Chuanzhi Liu, Xufeng Zang, Baohua Yu, Xiaochun Yu,* Qing Xu.* Microwave-Promoted TBAF-Catalyzed SNAr Reaction of Aryl Fluorides and ArSTMS: an Efficient Synthesis of Unsymmetrical Diaryl Thioethers. Synlett, 2011(8), 1143-1148 (SCI-III, IF: 2.655).

DOI:10.1055/s-0030-1259959

(46) Qing Xu, Ruwei Shen, Yutaka Ono, Ritsuko Nagahata, Shigeru Shimada, Midori Goto, Li-Biao Han.* A New Oxapalladacycle Generated via Ortho C-H Activation of Phenylphosphinic Acid: Efficient Catalyst for Markovnikov-Type Additions of E-H Bonds to Alkynes. Chem. Commun. 201147 (8), 2333-2335 (SCI-II, IF: 6.834).

DOI:10.1039/c0cc03436c

Organic Chemistry Portal摘录: www.organic-chemistry.org/Highlights/2011/31October.shtm

Labome摘录: http://www.ncbi.nlm.nih.gov/pubmed/21161095

(47) Qing Xu, Han, Li-Biao.* Metal-catalyzed additions of H-P(O) bonds to carbon-carbon unsaturated bonds. J. Organometallic Chem. 2011, 696 (1), 130-140 (SCI, IF: 2.0).

DOI:10.1016/j.jorganchem.2010.08.043

(48) Li-Biao Han,* Yutaka Ono, Qing Xu, Shigeru Shimada. Highly Selective Markovnikov-Type Addition of Hypervalent H-Spirophosphoranes to Alkynes Mediated by Palladium Acetate: Generality and Mechanism. Bull. Chem. Soc. Jpn. 2010, 83 (9), 1086-1099 (SCI-III, IF: 1.436).

DOI:10.1246/bcsj.20100141

(49) Qing Xu,* Li-Biao Han.* Transition Metal-Catalyzed Selective Hydrophosphorylation Reactions. Scientia Sinica Chimica, 2010, 40 (7), 802-826.

(50) Gang Wang, Ruwei Shen, Qing Xu, Midori Goto, Yufen Zhao,* Li-Biao Han.* Stereospecific Coupling of H-Phosphinates and Secondary Phosphine Oxides with Amines and Alcohols: a General Method for the Preparation of Optically Active Organophosphorus Acid Derivatives. J. Org. Chem. 2010, 75 (11), 3890-3892 (SCI-II, IF: 4.721).

   DOI:10.1021/jo100473s

(51) Qing Xu, Chang-Qiu Zhao, Li-Biao Han.* Stereospecific Nucleophilic Substitution of Optically Pure H-Phosphinates: A General Way for the Preparation of Chiral P-Stereogenic Phosphine Oxides. J. Am. Chem. Soc. 2008, 130 (38), 12648-12655 (SCI-I, IF: 12.113).

DOI:10.1021/ja804412k

被日本《化学工业日报》和研究同行高度评

Han教授相关系列工作20154月和9月分别获得日本科学技术奖(日本文部科学大臣表彰)和筑波奖励奖(つくば奨励賞)

(52) Qing Xu, Li-Biao Han.* Palladium-Catalyzed Asymmetric Hydrophosphorylation of Norbornenes. Org. Lett. 2006, 8 (10), 2099-2101 (SCI-II, IF: 6.364).

DOI:10.1021/ol060568y

(53) Qing Xu, Xian Huang,* Jingqi Yuan. Facile Synthesis of β-Organotellurobutenolides via Electrophilic Tellurolactonization of α-Allenoic Acids. J. Org. Chem. 2005, 70 (17), 6948-6951 (SCI-II, IF: 4.721).

DOI:10.1021/jo050564r

(54) Qing Xu, Xian Huang.* Cis-Carbocuperation of Acetylenic Sulfoxides and Corresponding Applications in the Regio- and Stereoselective Synthesis of Polysubstituted Vinyl Sulfoxides. Tetrahedron Lett. 2004, 45 (29), 5657-5660. (SCI-III, IF: 2.379)

DOI:10.1016/j.tetlet.2004.05.141

(55)  Qing Xu, Xian Huang,* Jun Ni. Hydrotelluration and Carbotelluration of Acetylenic Sulfoxides: Regio- and Stereoselective Preparation of α- and β-Organotellurovinyl Sulfoxides. Tetrahedron Lett. 2004, 45(14), 2981-2984 (SCI-III, IF: 2.379).

   DOI:10.1016/j.tetlet.2004.02.064

(56) Xian Huang,* Chun-Gen Liang, Qing Xu, Qi-Wen He. Alkyne-Based, Highly Stereo- and Regioselective Synthesis of Stereodefined Fucntionalized Vinyl Tellurides. J. Org. Chem. 2001, 66 (1), 74-80 (SCI-II, IF: 4.721).

   DOI:10.1021/jo001026b

授权专

(1)         Li-Biao Han, Qing Xu. Method for Producing Optically Active Phosphate Compounds. Japanese Patent JP2007-137831A.

(2)         Li-Biao Han, Qing Xu. Method for Producing Optically Active Phosphorus Compound. Japanese Patent JP2008-69103A.

(3)         俞磊、易容、陈天、吴于兰、徐清,《一种由醛肟合成腈的方法》,中国发明专利:ZL201110332796.7 (2013-09-18)

(4)         徐清、余小春、田海雯,《一种亚胺类化合物的合成方法》,中国发明专利:ZL201210007393.X (2014-07-16).

(5)         徐清、陈建辉、郑飞、张正平,《一种单烷基芴的合成方法》,中国发明专利:ZL201310072756.2 (2014-10-10).

(6)         徐清、余小春、李强,《一种醇与胺脱水合成胺类化合物的方法》,中国发明专利:ZL201210061107.8 (2014-11-06).

(7)         徐清、陈建辉、田海雯、袁雪勤、周崇款,《一种取代酮的绿色合成方法》,中国发明专利:ZL201310168583.4 (2014-11-06).

(8)         徐清、余小春、张二磊、徐义兰、周勇、俞磊,《一种由醛肟或醛和羟胺制备一级酰胺的方法》,中国发明专利:ZL201310016400.7 (2015-01-06).

(9)         徐清、陈浩楠、陈逸、戴武杰、仇晶晶,《一种由腈制备杂环化合物的绿色方法》,中国发明专利:ZL201310245469.7 (2015-01-03).

(10)     徐清、李双艳、李强,《一种氨基噻唑化合物的脱水烷基化方法》,中国发明专利ZL201310088068.5 (2015-04-15).

(11)     徐清、胡新根、陈平良,《一种对称和非对称脂肪醚的合成方法》,中国发明专利:ZL201310073115.9 (2015-04-28).

(12)     徐清、田海雯、尹新林、张鹏飞,《一种铜催化醇氧化制备醛和酮的绿色方法》,中国发明专利ZL201310245470.X (2015-05-06).

(13)     徐清、陈浩楠、万旭军,《一种制备二级和三级取代酰胺的方法》,中国发明专利ZL201210499023.2 (2015-05-11).

(14)     徐清、廖诗亨,《一种甲基酮的α-烷基化方法》,中国发明专利ZL201210348380.9 (2015-05-13).

(15)     徐清、史鑫康、郭俊梅、周斌,《一种苯并噻唑杂环化合物的绿色合成方法》,中国发明专利ZL201310399108.8 (2015-05-21).

代表

论著

徐清*、吴华悦,《亨利反应(Henry Reaction)》(胡跃飞教授、林国强院士主编《现代有机反应》第七卷第三章, pp 93-155),化学工业出版社,2013年。




(1)   国家自然科学基金面上项目醇的可控活化策略机理研究及其在碳-碳和碳-杂键绿色构建中的应用(项目号216721632017.1-2020.12,主持)

(2)   浙江省自然科学基金委杰出青年基金项目醇的绿色活化方法研究及其在碳-碳和碳-杂化合物合成中的应用项目号LR14B0200022014.01-2017.12,主持)

(3)   国家自然科学基金青年基金项目亚胺的绿色合成及其在有机药物中间体合成中的应用研究”(2014.01-2016.12,参与)

(4)   浙江省自然科学基金一般项目亚胺的绿色合成及其在药物中间体合成中的应用研究”2013.01-2015.12,参与)

(5)   国家自然科学基金青年基金项目光学活性磷手性磷氢化合物合成法开发及其绿色导入研究2010.01-2012.12,负责人,已结题)

(6)   教育部第40批留学回国人员科研启动基金光学活性磷手性磷氢化合物合成法开发及其绿色导入研究”(负责人)

(7)   浙江省自然科学基金一般项目环化官能团化反应合成有机碲代杂环化合物及其应用研究”(2010.06-2013.06,负责人,以优秀成绩结题)

(8)   浙江省钱江人才计划特殊急需类D类项目“光学活性磷手性化合物绿色合成法开发及其在药物合成中的应用2010.01-2012.12,负责人)

(9)   浙江省高等学校优秀青年教师资助计划项目官能团化环化反应研究及其在复杂分子合成中的应用2009.09-2011.10,负责人,已结题)





(1)       201612月,入选江苏省企业创新类“双创人才”(江苏恒安化工有限公司);

(2)       201512月,入选江苏省淮安市淮上英才计划 创新创业领军人才(江苏恒安化工有限公司);

(3)       201510月, 论文“Unexpectedly Simple Synthesis of Benzazoles by t-BuONa-Catalyzed Direct Aerobic Oxidative Cyclocondensation of o-Thio/Hydroxy/Aminoanilines with Alcohols under Air(Chem. Eur. J. 2015, 21, 9988) Advances in Engineering 评为“a Key Scientific Article contributing to excellence in engineering, scientific and industrial research”;

(4)       201410月,入选浙江省151人才工程第二层次;同年12月直接列入温州市“551人才工程第一层次;

(5)       20148月,论文Copper-Catalyzed N-Alkylation of Amides and Amines with Alcohols Employing the Aerobic Relay Race Methodology”(Org. Biomol. Chem. 2012, 10 (15), 2966-2972) 被评为2011-2012影响因子周期Org. Biomol. Chem.杂志top 10% of the most highly cited articles

(6)       20148月,论文Copper-Catalyzed C-Alkylation of Secondary Alcohols and Methyl Ketones with Alcohols Employing the Aerobic Relay Race Methodology”(Org. Biomol. Chem. 2012, 10 (15), 2973-2978) 被评为2011-2012影响因子周期Org. Biomol. Chem.杂志top 10% of the most highly cited articles

(7)       20145月,论文“Palladium-Catalyzed N-Alkylation of Amides and Amines with Alcohols Employing the Aerobic Relay Race Methodology”(Chin. J. Chem. 2012, 30, 2322-2332)入选 Chin. J. Chem.杂志 “one of the most accessed papers in Top 25 from 5/2013 to 4/2014”

(8)       20145月,入选第十三届温州市十大杰出青年

(9)       2014年,获浙江省自然科学基金委杰出青年基金;

(10)   201312月,论文Rhodium-Catalyzed Aerobic N-Alkylation of Sulfonamides with Benzylic Alcohols”(Chin. Chem. Lett. 201122 (9), 1021-1024)被评为《中国化学快报》2013年度高被引论文;

(11)   201311月,入选温州市“580海外精英引进计划同时入选温州市特聘专家

(12)   20139月,入选浙江省151人才工程第三层次;

(13)   20138月,论文“Palladium-Catalyzed N-Alkylation of Amides and Amines with Alcohols Employing the Aerobic Relay Race Methodology”(Chin. J. Chem. 2012, 30, 2322-2332)入选 Chin. J. Chem.杂志“one of the most accessed papers from 8/2012 to 7/2013”

(14)   20132月,论文Rhodium-Catalyzed Aerobic N-Alkylation of Sulfonamides with Benzylic Alcohols”(Chin. Chem. Lett. 201122 (9), 1021-1024)被评为《中国化学快报》2011年度优秀论文

(15)   201212月,《室温空气条件下直接温和的钯催化醇和胺有氧氧化合成亚胺的方法》获浙江省自然科学学术奖三等奖(排名1/4);

(16)   201212月,《过渡金属催化醇与胺有氧反应机理研究及应用》获浙江省高等学校优秀科研成果奖三等奖(排名1/2);

(17)   201212月,入选首届温州大学学生科技创新十佳指导教师

(18)   201211月,入选温州市新世纪551人才工程第二层次

(19)   20129月,论文“Direct and Mild Palladium-Catalyzed Aerobic Oxidative Synthesis of Imines from Alcohols and Amines under Ambient Conditions” (Chem. Commun. 2011, 47, 10833)被评为十一五浙江省自然科学基金优秀论文

(20)   200911月,入选浙江省高等学校优秀青年教师资助。

优秀硕士毕业生:

(1)   12级硕士 李晓慧:发表TetrahedronGreen Chem.等论文,考取厦门大学博士研究生;

(2)   11级硕士 陈建辉:发表 Angew. Chem.Adv. Synth. Catal.Green Chem.等论文;在校期间获11-12年度研究生二等奖学金、12-13年度研究生一等奖学金、2013年研究生国家奖学金、2014年浙江省优秀毕业生等荣誉称号;免试推荐攻读浙江大学博士研究生(导师:陆展研究员);

(3)   10级硕士 田海雯(女):发表 Adv. Synth. Catal.Angew. Chem.Chem. Commun.Org. Biomol. Chem.等论文;在校期间获10-1111-12年度研究生一等奖学金、2012研究生国家奖学金、2013年校级优秀毕业生、华峰院长奖等荣誉称号;考取复旦大学2013级博士研究生(导师:周锡庚教授);

(4)   10级硕士 吴于兰(女,扬州大学13届毕业生,与俞磊副教授联合培养):发表Org. Lett.Green Chem. 等论文;获2012年研究生国家奖学金;扬大化学化工学院优秀毕业生;江苏某大型药企工作;

(5)   09级硕士 李强:发表 Adv. Synth. Catal.Org. Biomol. Chem.J. Org. Chem.等论文;考取湖南大学12级博士研究生(导师:韩立彪教授);

(6)   09级硕士 姜澜(女):发表 Chem. Commun.Org. Lett.等论文;衢州巨化集团工作;

优秀本科毕业生:

(1)   06级本科生 臧旭峰:本课题组10届本科毕业论文学生,期间发表SynlettJ. Chem. Res.等论文;在校期间多次获得一等、二等奖学金、三好学生、优秀学生干部、优秀学生党务干部、校优秀毕业生等荣誉称号;考取华南理工大学10级硕士研究生,现转攻读博士研究生(导师:曹德榕教授);

(2)   06级本科生 邵羽裳(女):本课题组10届本科毕业论文学生;考取华东师范大学10级硕士研究生(导师:李艳忠教授);

(3)   06级本科生 谢建江:本课题组10届本科毕业论文学生;在校期间多次获得奖学金;考取南京理工大学10级硕士研究生(导师:李峰副教授);现就职于三门核电有限公司;

(4)   08级本科生 崔巍:本课题组12届本科毕业论文学生;考取华南理工大学12级硕士研究生(导师:曹德榕教授);

(5)   08级本科生 周勇:本课题组12届本科毕业论文学生;2011年国家励志奖学金、12级华东理工大学和上海有机所联合培养硕士研究生(导师:游书力研究员);

(6)   08级本科生 汪家宏:本课题组12届本科毕业论文学生;2011年国家励志奖学金、考取华东理工大学12级硕士研究生;

(7)   08级本科生 张俊:本课题组12届本科毕业论文学生;考取华东师范大学12级硕士研究生;

(8)   09级本科生 罗明部:本课题组13届本科毕业论文学生;考取福州大学13级硕士研究生;

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本课题组常年招收有机化学专业研究生,同时与深圳大学范滇元院士团队苏陈良博士合作招收绿色有机合成与催化方向博士后(待遇优厚、见下文链接),也欢迎热爱科研与学术的本科生同学参与本科毕业论文、省新苗人才计划、大学生创新创业训练计划等大学生科研创新项目!

 

http://www.wzu.edu.cn/Art/Art_67/Art_67_70983.aspx

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