温州大学化学与材料工程学院

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金辉乐

发布时间:2014-11-14 来源: 编辑: 点击[点击关闭]

    名:金辉乐

职称职务:高级实验师/化学实验中心副主任

    院:化学与材料工程学院

个人简介:

20141114111843975

          金辉乐,男,汉族,197912月出生,浙江瑞安,高级实验师,东华大学在职博士。20057月毕业于贵州大学生物化学与分子生物学专业,获理学硕士学位,分配到温州大学工作,现任温州大学化学与材料工程学院化学实验中心副主任。从事实验室管理与科学研究工作,是浙江省碳材料技术研究重点实验室和省教育厅纳米材料化学与应用创新团队的骨干成员。近五年来,主要从事微纳结构功能材料的可控合成及其在生化传感和能源等方面的应用研究。目前,主持国家自然科学基金、浙江省自然科学基金、浙江省有机化学与皮革化工重中之重学科预研基金及温州市科技局等项目,现已在J. Am. Chem. Soc.J. Power SourceBiosen.Bioelectron., J. Phys. Chem. C, Electrochem. Commun.等学术期刊上发表20多篇SCI论文。

研究方向:

主要从事微纳结构功能材料的可控合成及其能源(燃料电池、超级电容器、锂电池)等方面的应用研究。

科研项目:

1、主持,硫(-II)化合物氧化过程的电化学原位无标记表面增强拉曼光谱检测与调控,国家自然科学基金(21301130),30万,2014.01-2016.12.

2、主持,新型三维多孔石墨烯储能材料的可控合成与性能调控,浙江省自然科学基金(LY13E020008), 8万,2013.01-2015.12.

3、参与(第二),新颖异活性中心芳烃钌()配合物疏水亲水平衡与靶向作用的调控机制研究,国家自然科学基金(21371137),90万,2013.11-2017.12.

4、参与(第二),基于过渡金属/非金属原位共掺杂的多孔碳基非均相催化剂的设计、制备及其高效促进有机合成反应的研究,国家自然科学基金(51572198),64万,2016.01 – 2019.12.

5、参与(第二),基于过渡金属/非金属原位共掺杂多级孔碳材料的高效酸性燃料电池氧还原催化剂的设计、合成及性能研究,浙江省自然科学基金重点项目(LZ15E020002),30万,2015.01-2018.12.

6、参与(第五),新型三维多级结构石墨烯组装体的宏量合成、机理及性质研究,国家自然自然科学基金(51272182),80, 2013.01-2016.12.

7、参与(第四),基于纳米信号放大技术和组合电化学法研究G-四螺旋DNA与配体分子的相互作用,国家自然自然科学基金(2107313),40万,2011.01-2013.12

8、主持,以介孔沸石为载体开发温和条件下生产清洁柴油的高效催化剂,温州市科技局(G20090149),10万,2010.01-2011.12

9、主持,橡塑加工实训中心建设的探索与实践,温州市教育局, 2011.01-2011.12

代表性成果:

1、发表论文:

[1] Huile Jin; Huihui Huang; Yuhua He; Xin Feng; ShunWang;* Liming Dai*, Jichang Wang*. Graphene Quantum Dots Supported by Graphene Nanoribbons with Ultrahigh Electrocatalytic Performance for Oxygen Reduction, J. Am. Chem. Soc., 2015, 137(24), 7588–7591.

[2] Jianqiang Hu; Aili Liu; Huile Jin; Dekun Ma; Dewu Yin; Pengsheng Ling; Shun Wang*; Zhiqun Lin*; Jichang Wang*. A Versatile Strategy for Shish-Kebab-like Multi-heterostructured Chalcogenides and Enhanced Photocatalytic Hydrogen Evolution, J. Am. Chem. Soc., 2015, 137 (34), 11004–11010.

[3] Huile Jin; Demeng Wang; Yuewu Zhao; Huan Zhou; Shun Wang*; Jichang Wang*. Fabrication of Te@Au core-shell hybrids for efficient ethanol oxidation. J.Power Source, 215,227-232,2012.

[4] Hui-Le Jin; Tian-Xing Cheng; Jiu-Xi Chen*. Cerium-catalyzed tandem synthesis of 2-substituted benzothiazoles in PEG.  Appl. Organometal. Chem., 25(3), 238-240, 2011.

[5] Yuewu Zhao; Huile Jin*; Huan Zhou; Juanjuan Lin; Shun Wang*; Jichang Wang*. Fabrication of Te@Pd Core-shell Hybrids for Efficient C-C Coupling Reactions. J. Phys. Chem. C, 116, 7416-7420, 2012

[6] Wei Li, Yongfeng Bu, Huile Jin*, Jian Wang, Weiming Zhang, Shun Wang,* Jichang Wang*. The Preparation of Hierarchical Flowerlike NiO/Reduced Graphene Oxide Composites for High Performance Supercapacitor Applications. Energy Fuels, 27, 6304?6310,2013.

[7] Wang, J., Jin H. L., He Y. H., Lin D. J., Liu A. L, Wang S.*, Wang J.*, The selective formation of graphene ranging from two-dimensional sheets to three-dimensional mesoporous nanospheres. Nanoscale, 2014, 6, 7204-7208.

[8] Lin D. J.*, Mei C.Y., Liu A.L., Jin H.L., Wang S.*, Wang J., Cascade signal amplification for electrochemical immunosensing by integrating biobarcode probes, surface-initiated enzymatic polymerization and silver nanoparticle deposition, Biosen. Bioelectron., 2015, 66, 177-183.

[9] Guan L., Wang S.*, Gu W., Zhuang J., Jin H., Zhang W., Zhang T.*, Wang J.*. Ultrasensitive room-temperature detection of NO2 with telluriumnanotube based chemiresistive sensor. Sens. Actuators B: Chem., 2014, 196, 321-327.

[10] Demeng Wang, Shun Wang,*, Huile Jin, Weiming Zhang, Yun Yang, Aiping Sun, Tiandi Tang, and Jichang Wang*. Fabrication of noble-metal catalysts with a desired surface wettability and their applications in deciphering multiphase reactions. ACS Appl. Mater. Interf., 5, 3952-3958, 2013.

[11] Demeng Wang, Yuewu Zhao, Huile Jin,Jinxia Zhuang, Weiming Zhang, Shun Wang,* and Jichang Wang*. Synthesis of au-decorated tripod-shaped te hybrids for applications in the ultrasensitive detection of arsenic. ACS Appl. Mater.Interf.,5, 5733-5740, 2013.

[12] Shun Wang*, Ling Li, Huile Jin, TingYang, Weiwei Bao, Shaoming Huang, JichangWang*. Electrochemical detection of hepatitis Band papilloma virus DNAs using SWCNT array coated with gold nanoparticles. Biosen. Bioelectron., 41,205 -210,2013.

[13] Ting Yang, Shun Wang*, Huile Jin , Weiwei Bao, Shaoming Huang, Jichang Wang,*. An electrochemical impedance sensor for the label-free ultrasensitive detection of interleukin-6 antigen. Sens. Actuators B: Chem.,178, 310-315,2013.

[14] 孟晨鹏; 王舜*; 张克军; 金辉乐*; 陈锡安. 2-(5-氟尿嘧啶-1-乙酰基)氨基-1,5-戊二酸二甲酯手性异构体与双链/G-四链体DNA相互作用的电化学研究,化学学报, 69(10), 1173-1178, 2011.

[15] Feng Jiang; Shun Wang*; Ling Li; Huile Jin; Juanjuan Lin; Jichang Wang*. A rapid green route for fabricating efficient SERS substrates. Green Chem., 13(10), 2831–2836, 2011.

[16] Yongfeng Bu; Shun Wang*; Huile Jin; Weiming Zhang; Juanjuan Lin; Jichang Wang*. Synthesis of Porous NiO/Reduced Graphene Oxide Composites for Supercapacitors. J. Electrochem. Soc., 159(7), A990-A994, 2012.

[17]Shun Wang*; Ling Li; Huile Jin; Ting Yang; Weiwei Bao; Shaoming Huang; Jichang Wang*.  Electrochemical detection of hepatitis B and papilloma virus DNAs using SWCNT array coated with gold nanoparticles. Biosen. Bioelectron., 41(15), 205-210, 2013.

[18] Quan Hu; HuiLe Jin; XiAn Chen; Shun Wang *. Thermal and FTIR spectral studies of N,N′-diphenylguanidine, J. Therm.  Anal.  Calori., 110, 593–599, 2012.

[19] Quan Hu; KeJun Zhang; HuiLe Jin; XiAn Chen; MaoLin Hu; Shun Wang *. Electrochemical investigation on the interaction of benzene sulfonyl 5-fluorouracil derivatives with double-stranded DNA and G-quadruplex DNA. Sci. China Chem. 55(7), 1345-1350, 2012.

[20] Feng Jiang; Shun Wang*; Juanjuan Lin; Huile Jin; Lijie Zhang; Shaoming Huang; Jichang Wang*. Aligned SWCNTs - copper oxide array as a nonenzymatic electrochemical probe of glucose. Electrochem. Commun., 13, 363-365, 2011.

[21] Qingping Ke; Wenqian Fu; Huile Jin; Lei Zhang; Tiandi Tang*; Jingfeng Zhang, Fabrication of mechanically robust superhydrophobic surfaces based on silica micro-nanoparticles and polydimethylsiloxane. Surf. Coat. Technol., 205, 4910–4914, 2011.

[22]Yongfeng Bu; Shun Wang*; Qing Chen; Huile Jin; Juanjuan Lin; Jichang Wang*. Self-assembly of osmium complexes on reduced graphene oxide: A case study toward electrochemical chiral sensing. Electrochem. Commun, 16, 80–83, 2012.

[23] Jiu-Xi Chen; Chang-Fu Zhang; Wen-Xia Gao; Hui-Le Jin; Jin-Chang Ding;  Hua-Yue Wu*. B2O3/Al2O3 as a New, Highly Eficient and Reusable Heterogeneous Catalyst for the Selective Synthesis of β-Enamino Ketones and Esters under Solvent-Free Conditions. J. Braz. Chem. Soc., 21(8),1-5, 2010.

[24]Yali Xu; Jiuxi Chen; Wenxia Gao; Huile Jin; Jinchang Ding; Hua-Yue Wu*. Solvent-free synthesis of 3,5-di(hetero)aryl-1,2,4-thiadiazoles by grinding of thioamides under oxidative conditions, J. Chem. Res.,151–153, 2010.

[25]Shuanghua Cheng; Jiuxi Chen; Wenxia Gao; Huile Jin; Jinchang Ding; Hua-Yue Wu*. Oxidative esterification of aldehydes with alcohols and phenols in air, J. Chem. Res., 130–132, 2010.

[26] Jian Wang, Huile Jin, Yuhua He, Dajie Lin,Aili Liu,Shun Wang*, Jichang Wang* The selective formation of graphene ranging from two-dimensional sheets to three-dimensional mesoporous nanospheres , Nanoscale , 2040-3364 ,2014.

2、授权专利

[1] 金辉乐, 王舜, 赵岳五. 一种碲/钯核壳结构纳米晶催化剂及其制备方法与应用, 2011, 中国, 专利授权号: ZL 201110419974.X.

[2] 金辉乐, 王舜,卜永峰, 李蔚, 王健. 一种氯掺杂石墨烯及其制备方法与应用, 2013, 中国, 专利授权号: ZL 201310043338.0.

[3] 王舜, 王健,金辉乐. 一种氮掺杂介孔石墨烯微球及其制备与应用, 2015, 中国, 专利授权号: ZL 201310683949.1

[4] 王舜, 金辉乐, 卜永锋. 一种纳米氧化镍/石墨烯复合电极材料及制备方法和应用, 2011, 中国, 专利授权号: ZL 201110416687.3.

[5] 王舜, 金辉乐, 王德猛. 一种直接乙醇燃料电池高抗CO阳极催化剂及制备与应用, 2012, 中国, 专利授权号: ZL 201210066198.4.

[6] 王舜, 金辉乐, 王德猛, 赵岳五. 一种碲金复合材料及其制备与应用, 2013, 中国, 专利授权号: ZL 201310044241.1.

[7] 王舜, 金辉乐, 关雷. 一种碲纳米管及其制备方法与应用, 2013, 中国, 专利授权号: ZL 201310044498.7.

[8] 王舜, 金辉乐, 孙爱平. 一种双氧水传感器及制备方法与应用, 2013, 中国, 专利授权号: ZL 201310044200.2.

[9] 王舜, 金辉乐, 赵岳五. 一种碲半导体微纳米晶及制备方法, 2011, 中国, 专利授权号: ZL 201110419724.6.

[10] 王舜, 陈锡安, 金辉乐, 杨婷. 一种直接检测IL-6抗原的电化学免疫传感器及应用, 2012, 中国, 专利授权号: ZL 201210074963.7.

[11] 王舜, 关雷, 金辉乐. 一种海胆状硫化镉纳米球的制备方法, 2013, 中国, 专利授权号: ZL 201310193906.5.

[12] 王舜, 陈锡安, 李玲, 金辉乐. 一种基于单壁碳纳米管的超灵敏DNA生物传感器及制备方法和应用, 2011, 中国, 专利授权号: ZL 201110169043.9.

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