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夏远志,博士,副教授,硕士生导师。参与本专业的《高等有机化学》和《有机化学实验》的教学工作。

2004年6月毕业于湖北大学化学专业,获理学学士学位,同年9月考入中国科学院青海盐湖研究所攻读博士学位。期间,在北京大学余志祥教授和苏州大学李亚红教授的指导下从事物理有机化学和金属有机化学的研究工作;2009年6月获中国科学院研究生院理学博士学位。2009年7月加入温州大学化学与材料工程学院,先后担任讲师、副研究员、副教授,从事《有机化学》、《高等有机化学》、《有机化学实验》、《化学专业英语》等课程的教学工作和物理有机化学、金属有机化学等方面的科研工作。2012年到2013年是北京大学访问学者(合作导师:余志祥教授),2013年到2014年是德国弗莱堡大学访问学者(合作导师:Bernhard Breit教授)。目前已在J. Am. Chem. Soc.J. Org. Chem., Org. Lett.Chem. Eur. J.等国际著名期刊上发表研究论文近三十篇。应邀为J. Org. Chem.Organometallcs, Eur. J. Org. Chem.等国际杂志审稿。

夏远志博士是第59届“林岛诺贝尔奖获得者大会”特邀“青年学者”,2009年获中国科学院“院长优秀奖”。

在研项目:

1.      国家自然科学基金:有机反应中炔基金属卡宾中间体反应活性的理论与实验研究(21372178);

2.      浙江省自然科学基金:过渡金属催化邻炔基苯基衍生物环化反应的机理研究及新合成设计(LY13B020007);

3.      国家自然科学基金:一系列镍催化的有机反应机理的理论研究 (21002073);

4.      温州市科技计划:氟尿嘧啶氨基酸类化合物的计算机辅助设计合成及抗肿瘤活性(Y20100003)。

发表论文:

(*通讯作者):

(1)   Nam-Kyu Lee, Sang Young Yun, Phani Mamidipalli, Ryan M. Salzman, Daesung Lee*, Tao Zhou, and Yuanzhi Xia*, J. Am. Chem. Soc. 2014, 136, 4363.

(2)   Phani Mamidipalli,   Sang Young Yun,   Kung-Pern Wang,  Tao Zhou,   Yuanzhi Xia*, and   Daesung Lee*, Chem. Sci. 20145, 2362.

(3)   Tao Zhou, Liang Xu, and Yuanzhi Xia*, Org. Lett. 2013, 15, 6074.

(4)   Venkata R. Sabbasani, Phani Mamidipalli, Huijie Lu, Yuanzhi Xia, and Daesung Lee*, Org. Lett. 2013, 15, 1552.

(5)   Genping Huang, Yuanzhi Xia*, Chunrui Sun, Jingwei Li, and Daesung Lee*, “Theoretical Studies on the Mechanism of the C–H Amination of Silyl Cyclopropenes by Azodicarboxylates”. J. Org. Chem. 2013, 78, 988−995.

(6)   Chunrui Sun, Jingwei Li, Daesung Lee*, Genping Huang and Yuanzhi Xia*, “Formal C–H Amination of Cyclopropenes”. Chem. Commun. 2012, 48, 10990−10992.

(7)   Ji-Cheng Wu, Lu-Bing Gong, Yuanzhi Xia, Ren-Jie Song, Ye-Xiang Xie, Jin-Heng Li* “Nickel-Catalyzed Kumada Reaction of Tosylalkanes with Grignard Reagents to Produce Alkenes and Modified Arylketones”. Angew. Chem. Int. Ed. 2012, 51, 9909−9913.

(8)   Bo-Xiao Tang, Yue-Hua Zhang, Ren-Jie Song, Dong-Jun Tang, Guo-Bo Deng, Zhi-Qiang Wang, Ye-Xiang Xie, Yuan-Zhi Xia, and Jin-Heng Li*, “Intramolecular ipso-Halocyclization of 4-(p-Unsubstituted-aryl)-1-alkynes Leading to Spiro[4,5]trienones: Scope, Application, and Mechanistic Investigations”. J. Org. Chem. 2012, 77, 2837−2849.

(9)   Zhou Chen, Jian Wu, Yanmei Chen, Lei Li, Yuanzhi Xia*, Yahong Li*, Wei Liu, Tao Lei, Lijuan Yang, Dandan Gao, and Wu Li. “Rapid Accesses to Substituted Piperazines via Ti(NMe2)4-Mediated C-C Bond-Making Reactions”. Organometallics 2012, 31, 6005−6013.

(10) Genping Huang, Kelei Xie, Daesung Lee, Yuanzhi Xia*. “Reactivity of Alkynyl Metal-Carbenoids: DFT Study on the Pt-Catalyzed Cyclopropanation of Propargyl Ester-containing 1,3-Diynes”. Org. Lett. 2012, 14, 3850−3853.

(11) Bing Cheng, Genping Huang, Liang Xu, Yuanzhi Xia*. “Mechanism of the N-Protecting Group Dependent Annulations of 3-Aryloxy Alkynyl Indoles under Gold Catalysis: A Computational Study”. Org. Biomol. Chem. 2012, 10, 4417−4423.(影响因子:3.696;

(12) Liang Xu, Qi Zhu, Genping Huang, Bing Cheng, Yuanzhi Xia*. “Computational Elucidation of the Internal Oxidant-Controlled Reaction Pathways in Rh(III)-Catalyzed Aromatic C-H Functionalization”. J. Org. Chem. 2012, 77, 3017−3024. (Featured article, 封面文章). 

(13) Gengping Huang, Bing Cheng, Liang Xu, Yahong Li*, Yuanzhi Xia*. “Mechanism of the Transition Metal-Catalyzed Hydroarylation of Bromo-Alkyne Revisited: Hydrogen versus Bromine Migration”. Chem. Eur. J. 2012, 18, 5401−5415.

(14) Yuanzhi Xia*, Genping Huang. “Mechanisms of the Au- and Pt-Catalyzed Intramolecular Acetylenic Schmidt Reactions: A DFT Study”. J. Org. Chem. 2010, 75, 7842−7854.

(15) Yuanzhi Xia, Alexander S. Dudnik, Yahong Li*, Vladimir Gevorgyan*. “On the Validity of Au-vinylidenes in the Gold-Catalyzed 1,2-Migratory Cycloisomerization of Skipped Propargylpyridines”. Org. Lett. 2010, 12, 5538−5541.

(16) Yuanzhi Xia, A. S. Dudnik, V. Gevorgyan, Yahong Li* “Mechanistic Insighs into the Gold-Catalyzed Cycloisomerization of Bromoallenyl Ketones: Ligand-Controlled Regioselectivity”. J. Am. Chem. Soc. 2008, 130, 6940−6941.

(17) Yuanzhi Xia, Yong Liang, Yuanyuan Chen, Ming Wang, Lei Jiao, Feng Huang, Song Liu, Yahong Li, Zhi-Xiang Yu* “An Unexpected Role of a Trace Amount of Water in Catalyzing Proton Transfer in Phosphine-Catalyzed (3 + 2) Cycloaddition of Allenoates and Alkenes”. J. Am. Chem. Soc. 2007, 129, 3470−3471. 

(18)  Yuanzhi Xia, Yahong Li*, Wu Li “Theoretical Study on the Consecutive 1,2-Hydroboration and 1,1-Organoboration Reactions of Alkyn-1-yl(vinyl)silanes with Borane”. J. Organomet. Chem. 2008, 693, 3722−3728.

(19)  Yuanzhi Xia, Fengying Zhou, Yahong Li*, Wu Li. “Effect of Electron-withdrawing group on the [3,3]-Sigmatropic Rearrangements of 1,5-Enynes, 1,5-Diynes and 1,2-Diene-5-ynes: A Theoretical Study”. J. Mol. Struct. (THEOCHEM ) 2009, 904, 69−73.

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