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杨小平

发布时间:2014-10-28    来源:化学与材料工程学院    作者:    点击次    [点击关闭]

 


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                  介
   
                                                                                                                                                                                                                                                        
                      
杨小平,1969年11月出生,教授,中共党员,副院长。1991年毕业于江西大学(现南昌大学)化学系获理学学士学位,1996-2001年就读于中山大学化学与化工学院获理学博士学位,其后分别在香港浸会大学化学系(2002年)与美国德克萨斯大学奥斯汀分校化学系(2003-2012年)先后从事研究与教学工作。2012年加入温州大学化学与材料工程学院,2013年获“浙江省特聘专家”称号,2014年入选浙江省"钱江学者"特聘教授,2016年入选浙江省“151人才工程”第一层次。    

多年来一直从事新型功能材料的基础研究与发展工作,研究领域涉及超分子化学,纳米化学,功能金属配合物材料及生物成像等。已在国内外核心学术期刊上发表90多篇SCI论文,影响因子超过3.0的60多篇(其中包括1篇Angew. Chem. Int. Ed.,6篇J. Am.  Chem. Soc.,1篇Coord. Chem. Rev.和2篇Chem. Sci.)。同时,发表国际会议文章及简介20多篇,并在三部外文专著中撰写章节介绍研究成果。主持国家自然科学基金面上项目,参与获得2014年度教育部高等学校科学研究优秀成果奖二等奖。目前为多种国际学术核心期刊审稿人。

   
   
   
   
   
   
   
   
主要文章:                                                                                            
   

(1) Seyma G. Keskin, Xunjin Zhu, Xiaoping Yang, Alan H. Cowley and Bradley J. Holliday: "Luminescent electropolymerizable Ruthenium complexes and corresponding conducting metallopolymers" Macromolecules, 2018, accepted. (IF = 5.9)

(2) Hongfen Chen, Xiaoping Yang, Dongmei Jiang, Dongliang Shi and Lijie Zhang: "Construction of NIR luminescent polynuclear lanthanide-based nanoclusters with sensing properties towards metal ions" Dalton Trans., 2018, 47, 13880. (IF = 4.1)

(3) Dongmei Jiang, Xiaoping Yang, Xiaohui Zheng, Le Bo, Ting Zhu, Hongfen Chen, Lijie Zhang and Shaoming Huang: "Self-assembly of luminescent 12-metal Zn-Ln planar nanoclusters with sensing properties towards nitro explosives"      J. Mater. Chem. C, 2018, 6, 8513. (IF = 5.9)

(4) Ting Zhu, Xiaoping Yang, Xiaohui Zheng, Shiqing Wang, Le Bo, Chengri Wang, Hongfen Chen, Dongmei Jiang and Desmond Schipper: "Luminescent polynuclear Zn- and Cd-Ln square-like nanoclusters with a flexible long-chain Schiff base ligand" Front. in Chem., 2018, accepted. (IF = 4.1)

(5) Xiaoping Yang, Shiqing Wang, Yali Zhang, Guang Liang, Ting Zhu, Lijie Zhang, Shaoming Huang, Desmond Schipper and Richard A. Jones: "A self-assembling luminescent lanthanide molecular nanoparticle with potential for live cell imaging"     Chem. Sci., 2018, 9, 4630. (IF = 9.1)

(6) Le Bo, Shiqing Wang, Desmond Schipper, Xiaoping Yang, Ting Zhu and Junbin Tao: "Self-assembly of luminescent Zn–Ln (Ln = Sm and Nd) nanoclusters with a long-chain Schiff base ligand" New J. Chem., 2018, 42, 7241.(IF = 3.2)

(7) Chengri Wang, Xiaoping Yang, Shiqing Wang,Ting Zhu,Le Bo,Lijie Zhang, Hongfen Chen, Dongmei Jiang, Xiaomei Dong and Shaoming Huang: "Anion Dependent Self-assembly of drum-like 30- and 32-metal Cd-Ln Nanoclusters: Visible and NIR Luminescent Sensing of Metal Cations" J. Mater. Chem. C, 2018, 6, 865. (IF = 5.9)

(8) Shiqing Wang, Xiaoping Yang, Ting Zhu, Le Bo, Shaoming Huang, Chengri Wang, Dongmei Jiang, Hongfen Chen and Richard A. Jones: "Construction of Luminescent high-nuclearity Zn-Ln Rectangular Nanoclusters with Flexible Long-chain Schiff Base Ligands" Dalton Trans., 2018, 47, 53. (IF = 4.1)

(9) Xiaoping Yang, Shiqing Wang, Lijie Zhang, Chenri Wang, Ting Zhu, Le Bo and Shaoming Huang: "Enhancement of luminescence properties of high-nuclearity Cd-Ln (Ln = Eu and Nd) nanoclusters by the introdcution of secondary energy transfer donors" Nanoscale, 2017, 9, 517. (IF = 7.2)

(10) Shiqing Wang, Xiaoping Yang, Jinjie Qian, Qipeng Li, Zhongning Chen, Lijie Zhang, Shaoming Huang, Chengri Wang and R. A. Jones: "Anion dependent self-assembly of sandwich 13-metal Ni-Ln nanoclusters with a long-chain Schiff base ligand" Dalton Trans., 2017, 46, 1748. (IF = 4.1)

(11) Xiaoping Yang, Shiqing Wang, D. Schipper, Lijie Zhang, Zongping Li, Shaoming Huang, Daqiang Yuan, Zhongning Chen, A. Gnanam, J. Hall, T. King, E. Que, Y. Dieye, J. Vadivelu, K. Brown and R. A. Jones: "Self-assembly of high-nuclearity lanthanide-based nanoclusters for potential bioimaging applications" Nanoscale, 2016, 8, 11123. (IF = 7.2)

(12) Xiaoping Yang, Shiqing Wang, D. Schipper, K. Brown, R. A. Jones, Lijie Zhang and Shaoming Huang: "Self-assembly of luminescent high-nuclearity lanthanide-based nanoclusters with long-chain Schiff base ligands" Faraday Discuss., 2016, 191, 465. (IF = 3.4)

(13) Xiaoping Yang, Shiqing Wang, Lijie Zhang, Shaoming Huang, Zongping Li, Chengri Wang, Ting Zhu and Le Bo: "First NIR luminescent polymeric high-nuclearity Cd-Ln nanoclusters from a long-chain Schiff base ligand" J. Mater. Chem. C, 2016,4, 1589. (IF = 5.9)

(14) Yan Zhang, Pengchong Jiao, Haibing Xu, Mingjing Tang, Xiaoping Yang, Shaoming Huang and Jianguo Deng: "Switchable sensitizers stepwise lighting up lanthanide emission" Scientific Reports, 2015, 5, 9335. (IF = 4.1)

(15) K. Brown, Xiaoping Yang, D. Schipper, J. Hall, L. DePue, A. Gnanam, J. Arambula, J. Jones, J. Swaminathan, Y. Dieye, J. Vadivelu, D. Chandler, E. Marcotte, J. Sessler, L. Ehrlich and R. A. Jones: "A self-assembling lanthanide molecular nanoparticle for optical imaging" Dalton Trans., 2015, 44, 2667. (IF = 4.1)

(16) Xiaoping Yang, R. A. Jones and Shaoming Huang: "Luminescent 4f and d-4f Polynuclear Complexes and Coordination Polymers with Flexible Salen-type Ligand" Coord. Chem. Rev., (Review Article), 2014, 273-274, 63. (IF = 14.5)

(17) Xiaoping Yang, Zongping Li, Shiqing Wang, Shaoming Huang, D. Schipper and R. A. Jones: "Self-assembly of NIR luminescent 30-metal drum-like and 12-metal rectangular d-f nanoclusters with long-chain Schiff base ligands" Chem. Commun., 2014, 50, 15569. (IF = 6.2)

(18) Xiaoping Yang, D. Schipper, Lijie Zhang, Keqin Yang, Shaoming Huang, Jijun Jiang, Chengyong Su and R. A. Jones: "Anion depent self-assembly of 56-metal Cd-Ln nanoclusters with enchanced near-infrard luminescence properties" Nanoscale, 2014, 6, 10569. (IF = 7.2)

(19) R. A. Jones, A. Gnanam, J. Arambula, J. Jones, J. Saminathan, Xiaoping Yang, D. Schipper,J. Hall,L. DePue, Y. Dieye, J. Vadivelu, D.Chandler, E. Marcotte, J. Sessler, L. Ehrlich and K. Brown: “Lanthanide Nano-drums: "A New Class of Molecular Nanoparticles for Potential Biomedical Applications" Faraday Discuss., 2014, 175, 241. (IF = 3.4)

(20) Xiaoping Yang, D. Schipper, R. A. Jones, L. Lytwak, B. J. Holliday and Shaoming Huang: "Anion Dependent Self-assmbly of NIR Luminescent 24- and 32-metal Cd-Ln Complexes with Drum-like Architectures" J. Am. Chem. Soc., 2013, 135, 8468. (IF = 14.3)

(21) Xiaoping Yang, M. Oye, R. A. Jones and Shaoming Huang: "Anion Dependent Self-Assembly of a Linear Hexanuclear Yb(III) Salen Complex with Enhanced Near-infrared (NIR) Luminescence Properties" Chem. Commun., 2013, 49, 9579. (IF = 6.2)

(22) J. Cai, B. Hay, N. Young, Xiaoping Yang and J. Sessler: "A pyrrole-based triazolium-phane with NH and cationic CH donor groups as a receptor for tetrahedral oxyanions that functions in polar media" Chem. Sci., 2013, 4, 1560. (IF = 9.1)

(23) Shengchun Chen, Zhihui Zhang, Qun Chen, L. Wang, J. Xu, Minyang He, Miao Du, Xiaoping Yang and R. A. Jones: "An efficient strategy to achieve hydrophilic polymeric silver(I) materials with exceptional antibacterial activity" Chem. Commun., 2013, 49, 1270. (IF = 6.2)

(24) Z. Zhang, J. M. Lim, M. Ishida, V. Roznyatovskiy, V. Lynch, H.-Y. Gong, Xiaoping Yang, D. Kim and J. Sessler: "Cyclo[m]pyridine[n]pyrroles: Hybrid Macrocycles That Display Expanded pi-Conjugation Upon Protonation" J. Am. Chem. Soc., 2012, 134, 4076. (IF = 14.3)

(25) Xiaoping Yang, C. Chan, D. Lam, D. Schipper, J. M. Stanley, X. Chen, R. A. Jones, B. J. Holliday, W.-K. Wong, S. Chen and Q. Chen: "Anion-dependent construction of two hexanuclear 3d-4f complexes with a flexible Schiff base ligand" Dalton Trans., 2012, 41, 11449. (IF = 4.1)

(26) Sen Liao, Xiaoping Yang and R. A. Jones: "Self-assembly of Luminescent Hexanuclear Lanthanide Salen Complexes" Crystal Growth & Design, 2012,12, 970. (IF = 4.0)

(27) W. J. MeCarty, Xiaoping Yang, L. J. DePue and R. A. Jones: "Chemical vapour deposition of amorphous Ru(P) thin films from Ru trialkylphosphite hydride complexes" Dalton Trans., 2012, 41, 13496. (IF = 4.1)

(28) W. McCarty, X iaoping Yang, L. J. DePue and R. A. Jones: "Dinuclear Rh (II) pyrazolates as CVD precursors for rhodium thin films" Dalton Trans., 2012, 41, 173. (IF = 4.1)

(29) W. McCarty, Xiaoping Yang and R. A. Jones: "Synthesis, structure and DFT study of a pyrazolate stabilized mononuclear Rh(II) complex" Chem. Commun., 2011, 47, 12164. (IF =6.2)

(30) Xiaoping Yang, D. Lam, C. Chan, J. M. Stanley, R. A. Jones, B. J. Holliday and W.-K. Wong: "Construction of 1-D 4f and 3d-4f Coordination Polymers with Flexible Schiff Base Ligands" Dalton Trans., 2011, 40, 9795. (IF = 4.1)

(31) J. Cai, Xiaoping Yang, K. Arumugam, C. W. Bielawski and J. Sessler: "Structurally Characterized Cationic Silver(I) and Ruthenium(II) carbene complexes of 1,2,3-Triazol-4-ylidenes" Organometallics, 2011, 30(18), 5033. (IF = 4.0)

(32) Xiaoping Yang, R. A Jones, M. M. Oye,M. Wiesterand R. Lai: "Influence of Metal-Ligand Ratio on Benzimidazole Based Luminescent Lanthanide Complexes: 3-D Network Structures and Chloride Anion Binding" New J. Chem., 2011,3 5, 310. (IF = 3.2)

(33) X. Zhu, W.-K. Wong, W.-Y. Wong and Xiaoping Yang: "Design and Synthesis of Near-Infrared Emissive Lanthanide Complexes" Eur. J. Inorg. Chem., (Review Article) 2011, 4651. (IF = 2.5)

(34) J. Sessler, J. Cai, H. Gong, Xiaoping Yang, J. Arambula and B. Hay: "A Pyrrolyl-Based Triazolophane: A Macrocyclic Receptor With CH and NH Donor Groups That Exhibits a Preference for Pyrophosphate Anions" J. Am. Chem. Soc., 2010, 132, 14058. (IF = 14.3)

(35) J. Hall, Xiaoping Yang and R. A. Jones: "Syntheses and structures of the tetra-phosphine complexes trans-MCl2(PH3)4(M = Ru, Os)" Chem. Commun., 2010, 46, 6168. (IF = 6.2)

(36) Xiaoping Yang, R. A Jones, M. Wiester, M. M. Oye and W.-K. Wong: "Transformation of a Luminescent Benzimidazole Based Yb3Cluster into a 1-D Coordination Polymer" Crystal Growth & Design, 2010, 10(2), 970. (IF = 4.0)

(37) X. Chen, Xiaoping Yang and B. J. Holliday: "Metal-controlled Assembly of Near-infrared Emitting Pentanuclear Lanthanide-β-diketone Clusters" Inorg. Chem., 2010, 49, 2583. (IF = 4.7)

(38) J. Stanley, X. Zhu, Xiaoping Yang and B. J. Holliday: "Europium Complexes of a Novel Ethylenedioxythiophene (EDOT)-derivatized Bis(pyrazolyl)pyridine Ligand Exhibiting Efficient Lanthanide Sensitization" Inorg. Chem., 2010, 49, 2035. (IF = 4.7)

(39) K. Agapiou, R. A. Joens and Xiaoping Yang: "Acetylide and triazolato complexes from Ru(II) azides" Main Group Chemistry, 2010, 9, 41.

(40) A. Liao, Xiaoping Yang, J. Stanley, R. A. Jones and B. J. Holliday: "Synthesis and Crystal Structure of a New Heterotrinuclear Schiff-Base Zn-Gd Complexes" J. Chem. Cryst., 2010, 40, 1060.

(41) T. Hesterberg, Xiaoping Yang and B. J. Holliday: "Polymerizable cationic iridium(III) complexes exhibiting color tunable light emission and their corresponding conducting metallopolymers" Polyhedron, 2010, 29 (Special 2009 Young Investigator Issue), 110.

(42) M. Mejia, K. Agapiou, Xiaoping Yang and B. J. Holliday: "Seeded Growth of CdS Nanoparticles within a Conducting Polymer Matrix" J. Am. Chem. Soc., 2009, 131, 18196. (IF = 14.3)

(43) Xiaoping Yang, R. A. Jones, J. Rivers and W.-K. Wong: "Syntheses, Structures, and Photoluminescence of 1-D Lanthanide Coordination Polymers" Dalton Trans., 2009, 47, 10505. (IF = 4.1)

(44) S. Zhao, X. Lü, A. Hou, W.-Y. Wong, W.-K. Wong, Xiaoping Yang and R. A. Jones: "Heteronuclear Trimetallic and 1-D Polymeric 3d-4f Schiff-base Complexes with NCO-and NCS-Ligands" Dalton Trans., 2009, 43, 9595. (IF = 4.1)

(45) K. Agapiou, M. Mejia, Xiaoping Yang and B. J. Holliday: "Multinuclear Cd2, Cd3and 1-D framework structures of Cd(II) Schiff base complexes" Dalton Trans., 2009, 4154. (IF = 4.1)

(46) X. Chen, Xiaoping Yang and B. J. Holliday: "Photoluminescent Europium-Containing Inner Sphere Conducting Metallopolymer" J. Am. Chem. Soc., 2008, 130, 1546. (IF = 14.3)

(47) Xiaoping Yang, R. A. Jones and W.-K. Wong: "Anion depend self-assembly and the first X-ray structure of a neutral homoleptic lanthanide salen complex Tb4(salen)6" Chem. Commun., 2008, 3266. (IF = 6.2)

(48) Xiaoping Yang, R. A Jones and W.-K. Wong: "Pentanuclear Tetra-Decker Luminescent Lanthanide Schiff Base Complexes" Dalton Trans., 2008, 1676. (IF = 4.1)

(49) Xiaoping Yang, J. Rivers, M. Wrester and R. A. Jones: "Synthesis and structures of luminescent ladder-like lanthanide coordination polymers of 4-hydroxybenzenesulfonate" New J. Chem., 2008, 32, 790. (IF = 3.2)

(50) Xiaoping Yang, B. Hahn, R. A. Jones, W.-K. Wong and K. Stevenson: "Synthesis of an Octanuclear Eu(III) Cage from Eu42+: Chloride Anion Encapsulation, Luminescence and Reversible MeOH Adsorptionviaa Porous Supramolecular Architecture" Inorg.Chem., 2007, 46, 7050. (IF = 4.7)

(51) Xiaoping Yang, R. A. Jones, J. Rivers and R. P.-J. Lai: "Syntheses, Structures and Luminescent Properties of New Lanthanide-Based Coordination Polymers Based on 1,4-Benzenedicarboxylate (BDC)" Dalton Trans., 2007, 3936. (IF = 4.1)

(52) A. Waheed, R. A. Jones, K. Agapiou, Xiaoping Yang, J. Moore and J. G. Ekerdt: "Synthesis and Structures of Dinuclear 3,5-Bis(trifluoromethyl)pyrazolate Complexes of Ruthenium" Organometallics, 2007, 6778. (IF = 4.0)

(53) Xiaoping Yang, B. Hahn, R. A. Jones, K. Stevenson, J. Swinnea and Q. Wu: "Reversible guest molecule encapsulation in the 3-D framework of a heteropolynuclear luminescent Zn3Eu2cage complex" Chem.Commun., 2006, 3827. (IF = 6.2)

(54) Xiaoping Yang, R. A. Jones, W.-K. Wong, V. Lynch, M. M. Oye and A. Holmes: "Design and Synthesis of a Near Infra-Red Luminescent Hexanuclear Zn-Nd Prism" Chem. Commun., 2006, 1836. (IF = 6.2)

(55) Xiaoping Yang, R. A. Jones, M. M. Oye, A. Holmes and W.-K. Wong: "Near infrared luminescence and supramolecular structure of a helical triple-decker Yb(III) Schiff base cluster" Crystal Growth & Design,2 006, 2122. (IF = 4.0)

(56) W.-K. Lo, W.-K. Wong, W.-Y. Wong, J. Guo, K.-T. Yeung, Y.-K. Cheng, Xiaoping Yang and R. A. Jones: "Heterobimetallic Zn(II)-Ln(III) Phenylene-Bridged Schiff Base Complexes, Computational Studies and Evidence for Singlet Energy Transfer as the Main Pathway in the Sensitization of Near-Infrared Nd3+Luminescence" Inorg. Chem., 2006, 9315. (IF = 4.7)

(57) W.-K. Wong, Xiaoping Yang, R. A. Jones, J. Rivers, V. Lynch, W.-K. Lo, D. Xiao, M. M. Oye and A. Holmes: "Multinuclear Luminescent Schiff-Base Zn-Nd Sandwich Complexes" Inorg. Chem.,2 006, 45, 4340. (IF = 4.7)

(58) Xiaoping Yang and R. A. Jones: "Anion Dependent Self-Assembly of 'Tetra Decker' and 'Triple-Decker' Luminescent Tb(III) Salen Complexes" J. Am. Chem. Soc.,2 005, 127, 7686. (IF = 14.3)

(59) Xiaoping Yang, R. A. Jones, V. Lynch, M. M. Oye and A. Holmes: "Synthesis and near infrared luminescence of a tetrametallic Zn2Yb2architecture from a trinuclear Zn3L2Schiff base complex" Dalton Trans., 2005, 5, 849. (IF = 4.1)

(60) Xiaoping Yang, R. A. Jones and M. Wiester: "Nanoscale slipped sandwich of Tb10-stabilization of a benzaldehyde methyl hemiacetyl" Dalton Trans., 2004, 12, 1787. (IF = 4.1)

(61) A. Waheed, R. A. Jones, J. McCarty and Xiaoping Yang: "Synthesis and structure of Zn7(O)2(OAc)10(Pz)2(OAc = acetate; Pz = pyrazine)" Dalton Trans., 2004, 22, 3840. (IF = 4.1)

(62) Xiaoping Yang, Bei-Sheng Kang, Wai-Kwok Wong, Cheng-Yong Su and Han-Qin Liu: "Syntheses, Crystal Structures, and Luminescent Properties of Lanthanide Complexes with Tripodal Ligands Bearing Benzimidazole and Pyridine Groups" Inorg. Chem., 2003, 42, 169. (IF = 4.7)

(63) Cheng-Yong Su, Xiaoping Yang, Bei-Sheng Kang and Thomas C. W. Mak: "Thsymmetric nanoporous network built of hexameric metallamacrocycles with disparate cavities for guest inclusion" Angew. Chem. Int. Ed. Engl., 2001, 40, 1725. (IF = 12.1)

(64) Xiaoping Yang, Cheng-Yong Su, Bei-Sheng Kang, Xiao-Long Fong, Wen Xiao and Han-Qin Liu: "Studies on lanthanide complexes of the tripodal ligand N,N-bis(2-benzimidazolylmethyl)-N-(2-pyridylmethyl)amine. Crystal structures and luminescence properties" Dalton Trans., 2000, 19, 3253. (IF = 4.1)

(65) Cheng-Yong Su, Xiaoping Yang, Bei-Sheng Kang, Kai-Bei Yu, Ye-Xiang Tong and Thomas C. W. Mak: "Syntheses and crystal structures of methyl 2-pyridylmethylidene hydrazinedarbodithionte and its copper complexes" Bull. Chem. Soc. Jpn., 1999, 72, 2217.

   

专著:

(1) Xiaoping Yang, Shiqing Wang, Chengri Wang, Shaoming Huang and R. A. Jones: "Construction and luminescence properties of 4f and d-4f clusters with salen-type Schiff base ligands" <<Recent Development in Clusters of Rare Earths and Actinides: Chemistry and Materials>> 2016, Springer-Verlag GmbH.

(2) Xiaoping Yang and Richard A. Jones: "Luminescent Lanthanide Complexes with Multidentate Ligands" <<The Rare Earth Elements: Fundamentals and Application>> 2012, Editors: David Atwood and Kerry Powell, John Wiley & Sons, Ltd..

(3) Richard A. Jones and Xiaoping Yang: "New Complexes of Lanthanide with Unusual Main Group Ligands" <<Modern Aspects of Main Group Chemistry>> 2006, Editors: Michael Lattman and Richard A. Kemp.

        

  

   誉
   和
   获
   奖

12016年浙江省"151人才工程"第一层次

22014年温州市"551人才工程"第一层次

32014年浙江省高等学校"钱江学者"(特聘教授)

42014年度教育部高等学校科学研究优秀成果奖二等奖(参与)

52014年度温州市科学技术进步二等奖(参与)

62013年"浙江省特聘专家"

       

  基金

 

12017年国家自然科学基金,面上项目,主持(21771141

22014年度浙江省留学人员科技活动小额资助,主持(20150103

 

                                                                                                                                                                                                                                                                                       
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