代表论著 |
近年来发表文章如下: (59). Zhang, X.-G.; Dai, H,-X.; Wasa, M.; Yu, J.-Q.*, Pd(II)-Catalyzed Ortho Trifluoromethylation of Arenes and Insights into the Coordination Mode of Acidic Amide Directing Groups, J. Am. Chem. Soc., 2012, 134, 11948-11951. (58). Guo, Y.-Q.; Chen, F.*; Deng, C.-L.; Zhang, X.-G.*, Iodine-promoted ring-opening methylation of benzothiazoles with dimethyl sulfite, Chem. Comm., 2021, 57, 1923-1926. (57). Shen, X.-Q.; Wang, S.-Q.; Fan, D.; Zhang, X.-G.*; Tu, H.-Y.*; Copper-Catalyzed Selective Defluorinative Sulfuration of Trifluoropropanamides Leading to α-Fluorothioacrylamides, J. Org. Chem. 2021, 86, 1591-1600. (56). Zhang, Z.-Z.; Chen, R.; Zhang, X.-H.*; Zhang, X.-G.*, Synthesis of Isoselenazoles and Isothiazoles from Demethoxylative Cycloaddition of Alkynyl Oxime Ethers, J. Org. Chem. 2021, 86, 632-642. (55). He, S.-Y.; Zhang, X.-G.*, Palladium-catalyzed selective defluorinative sulfenylation for the synthesis of fluorovinylthioethers, Org. Chem. Front., 2020, 7, 3174-3178. (54). Hu, B.-L.; Song, Y.-K.; Zhang, G.; Yao, Z. Zhang, X.-G.*, Copper-catalyzed three component C–S/C–N coupling for the synthesis of trifluorothioacetamides, J. Fluorine Chem. 2020, 239, 109640. (53). Wang, S.-Q.; Yan, X.-W.*; Hu, B.-L.; Zhang, X.-G.*, Transition-metal and base-free thioannulation of propynamides with sodium sulfide and dichloromethane for the selective synthesis of 1,3-thiazin-4-ones and thiazolidine-4-ones, Tetrahedron, 2020, 76, 131021. (52). Li, L.; Chen, Q.; Xu, H.-H.; Zhang, X.-H.*; Zhang, X.-G.*, DBU-Promoted Demethoxylative Thioannulation of Alkynyl Oxime Ethers with Sulfur for the Synthesis of Bisisothiazole-4-yl Disulfides, J. Org. Chem. 2020, 85, 10083-10090. (51). Xu, H.-H.; Zhang, X.-H.*; Zhang, X.-G.*, Thioamidation of Arylpropyne Derivatives with Sulfur and Formamides for the Synthesis of Aryl Propanethioamides, Asian J. Org. Chem. 2020, 9, 111-115. (50). Xu, H.-H.; Zhang, X.-H.*; Zhang, X.-G.*, Copper-Catalyzed Tandem Sulfuration/Annulation of Propargylamines with Sulfur via C−N Bond Cleavage, J. Org. Chem. 2019, 84, 7894-7900. (49). He, S.-Y.; Xiong, J.*; Hu, B.-L.; Zhang, X.-G.*, Copper-catalyzed tandem cyclization and vinylation for the synthesis of 2-trifluoromethyl benzofurans, J. Fluorine Chem. 2019, 228, 109418. (48). Li, L.; Zhang, X.-G.*; Hu, B.-L.; Zhang, X.-H.*, Copper-Catalyzed Electrophilic Cyclization of N-Propargylamines with Sodium Sulfinate for the Synthesis of 3-Sulfonated Quinolines, Chem. Asian J. 2019, 14, 4358-4364. (47). Zhou, X.-C.; Hei, Y.-Y.; Song, J.-L.; Qian, P.-C.; Zhang, X.-G.*; Deng, C.-L.*, Copper-catalyzed direct C–H phosphorylationof N-imino isoquinolinium ylides with H-phosphonates, Org. Chem. Front., 2019, 6, 1453-1457. (46). Zhou, M.; Zhang, J.; Zhang, X.-G.*; Zhang, X.*, Ni-Catalyzed Defluorination for the Synthesis of gem-Difluoro-1,3-dienes and Their [4 + 2] Cycloaddition Reaction, Org. Lett. 2019, 21, 671-674. (45). Wang, S.-Q.; Hu, B.-L.; Zhang, X.-G.*, Copper-Catalyzed Thioannulation of Propynamides with Sodium Sulfide for the Synthesis of Isothiazol-3-ones, Adv. Synth. Catal. 2019, 361, 1459-1462. (44). Wei, F.; Zhang, X.-G.*, Organophosphine-free copper-catalyzed isothiocyanation of amines with sodium bromodifluoroacetate and sulfur, Chem. Comm., 2019, 55, 1144-1147. (43). Zhang, T.; Chen, F.*; Zhang, X.-H.; Qian, P.-C.; Zhang, X.-G.*, , Palladium-Catalyzed Tandem Carbocyclization and Hetroarylation for the Synthesis of 2-(Trifluoromethyl)indenylmethyleneindoles, J. Org. Chem., 2019, 84, 307-313. (42). Wei, F.; Shen, X.-Q.; Zhang, X.-H.; Zhang, X.-G.*, Copper-Catalyzed Defluorinative Thioannulation of Trifluoropropynes for the Synthesis of 1,2-Dithiole-3-thiones, Adv. Synth. Catal. 2018, 360, 3911-3915. (41). Li, X.-F.; Zhang, X.-G.*, Chen, F.; Zhang, X.-H.*, Copper-Catalyzed N- Formylation of Amines through Tandem Amination/Hydrolysis/Decarboxylation Reaction of Ethyl Bromodifluoroacetate, J. Org. Chem., 2018, 83, 12815-12821. (40). Li, X.-F.; Shi, L.-F.; Zhang, X.-G.*; Zhang, X.-H.*, Pd-Catalyzed C(sp2)–H aminocarbonylation using the Langlois reagent as a carbonyl source, Org. Biomol. Chem., 2018, 16, 6438-6442. (39). Li, X.-F.; Zhang, X.-G.*, Hu, B.-L.; Zhang, X.-H.*, Palladium-catalyzed dimerization of N-aryl propargylamines for the synthesis of 3-vinylquinolines, Org. Biomol. Chem., 2018, 16, 1736-1744. (38). Zhou, M.; Wang, F.; Zhang, X.-H.*; Tu, H.-Y.; Zhang, X.-G.*, Photoredox-catalyzed chloroalkylation and dimerization of styrenes with CF3CCl3 and CCl4, J. Fluorine Chem., 2018, 215, 10-16. (37). Wei, F.; Shen, X.-Q.; Chu, J.-J.; Hu, B.-L.; Zhang, X.-G.*, Palladium-catalyzed intramolecular aerobic C-H amination of enamines for the synthesis of 2-trifluoromethylindoles, Tetrahedron, 2018, 74, 720-725. (36). Wang, F.; Zhang, T.; Tu, H.-Y.; Zhang, X.-G.*, Transition-Metal-Free Conversion of Trifluoropropanamides into Cyanoformamides through C-CF3 Bond Cleavage and Nitrogenation, J. Org. Chem., 2017, 82, 5475-5480. (35). Wang, F.; Hu, B.-L.; Liu, L.; Tu, H.-Y.; Zhang, X.-G.*, One-Pot Synthesis of Quinoxalinones via Tandem Nitrosation/Cyclization of N-Aryl Cyanoacetamides, J. Org. Chem., 2017, 82, 11247-11252. (34). Liu, Y.; Hu, B.; Zhang, X.-G.*, Copper Catalyzed Iodosulfenylation of Styrenes by Dual C-H Oxidative Functionalization, Chin. J. Chem., 2017, 35, 307-310. (33). Lin, Y.-F.; Wang, C; Hu, B.-L.; Qian, P.-C.; Zhang, X.-G.*, Iron-Catalyzed Thiocyclization for the Synthesis of Trifluoromethylated Benzothiophenes by C-H Functionalization of Aryl Disulfides, Synlett, 2017, 28, 707-712. (32). Zhang, X.-S.; Jiao, J.-Y.; Zhang, X.-H.*; Hu, B.-L.; Zhang, X.-G.*, Synthesis of 2-Sulfenylindenones via One-Pot Tandem Meyer-Schuster Rearrangement and Radical Cyclization of Arylpropynols with Disulfides, J. Org. Chem., 2016, 81, 5710-5716. (31). Chu, J.-J.; Hu, B.-L.; Liao, Z.-Y.; Zhang, X.-G.*, Copper-Catalyzed Three-Component Tandem Cyclization for One-Pot Synthesis of 1,4-Benzothiazine, J. Org. Chem., 2016, 81, 8647-8652. (30). Song, Y.-K.; Qian, P.-C.; Chen, F.*; Deng, C.-L.; Zhang, X.-G.*, Synthesis of 2-(trifluoromethylthio)-indenones by silver-mediated cascade trifluoromethylthiolation/cyclization of arylpropynones, Tetrahedron, 2016, 72, 7589-7593. (29). Tu, H.-Y.; Hu, B.-L.; Deng, C.-L.; Zhang, X.-G.*, Copper-mediated stereospecific C–H oxidative sulfenylation of terminal alkenes with disulfides, Chem. Comm., 2015, 51, 15558-15561. (28). Liu, Y.; Tu, H.-Y.; Zhang, X.-G.*, Silver-Catalyzed Tandem Trifluoromethylation and Cyclization of Aryl Isonitriles with the Langlois Reagent, Synthesis, 2015, 47, 3460-3466. (27). Yao, B.; Deng, C.-L.; Liu, Y.; Tang R.-Y.; Zhang, X.-G.*; Li, J.-H.*, Palladium-catalyzed oxidative carbamoylation of isoquinoline N-oxides with formylamides by means of dual C–H oxidative coupling, Chem. Comm., 2015, 51, 4097-4100. (26). Qiu, J.-W.; Hu, B.-L.; Zhang, X.-G.*; Tang R.-Y.; Zhong, P.; Li, J.-H.*, Copper-catalyzed ring expansion of 2-aminobenzothiazoles with alkynyl carboxylic acids to1,4-benzothiazines, Org. Biomol. Chem., 2015, 13, 3122-3127. (25) Zhang, X.-S.; Li, G.-X.; Zhang, X.-G.*; Zhang, X.-H. *, Pd(II)-catalyzed selective sulfenylation of arene C-H bonds using N-arylthiobenzamides as thiolation reagent and oxidant, Tetrahedron, 2015, 71, 5458-5464. (24). Yang, Z.-J.; Liu, C.-Z.; Hu, B.-L.; Deng, C.-L.; Zhang, X.-G.*, Oxidative tandem nitrosation/ cyclization of N-aryl enamines with nitromethane toward 3-(trifluoromethyl)quinoxaline, Chem. Comm., 2014, 50, 14554-14557. (23). Tu, H.-Y.; Liu, Y.-L.; Chu, J.-J.; Hu, B.-L.; Zhang, X.-G.*, FeCl3 Promoted Carboxamidation and Cyclization of Aryl Isonitriles with Formamides toward Phenanthridine-6-carboxamides, J. Org. Chem., 2014, 79, 9907-9912. (22). Yang, Z.-J.; Hu, B.-L.; Deng, C.-L.; Zhang, X.-G.*, Iron-Promoted Electrophilic Annulation of Aryl Enynes with Disulfides or Diselenides Leading to Polysubstituted Naphthalenes, Adv. Synth. Catal. 2014, 356, 1962-1966. (21). Wang, W.-Y.; Hu, B.-L.; Deng, C.-L.; Zhang, X.-G.*, One-pot Synthesis of 3-Trifluoromethyl -benzofurans via Tandem Iodocyclization and Trifluoromethylation of 2-Alkynylanisoles, Tetrahedron Lett., 2014, 55, 1501-1503. (20). Wang, C.; Chen, L.-H. *; Deng, C.-L.; Zhang, X.-G.*, Synthesis of 3‑Trifluoromethylbenofurans via Palladium-Catalyzed Tandem Elimination/ Annulation of β-Chloro-β-(trifluoromethyl)styrenes with 2-Halophenols, Synthesis, 2014, 46, 313-319. Highlighted by Synfacts, 2014, 10, 132. (19). Wang, W.-Y.; Feng, X.; Hu, B.-L.; Deng, C.-L.; Zhang, X.-G.*, Synthesis of 6‑(Trifluoromethyl)phenanthridines via Palladium-Catalyzed Tandem Suzuki/C−H Arylation Reactions, J. Org. Chem., 2013, 78, 6025-6030. (18). Hu, B.-L.; Li, C.-L.; Liao, Z.-Y.; Zhang, X.-G.*, Tetrabutylammonium Bromide Catalyzed Tandem Addition/Cyclization of o-Aralkynylaryl Aldehydes with Trimethyl(trifluoromethyl) -silane: Synthesis of Trifluoromethyl Group Containing Phthalans, Synlett, 2013, 24, 2748-2750. (17). Dai, H.-X.; Li, G.; Zhang, X.-G., Stepan, A. F.; Yu, J.-Q.*, Pd(II)-Catalyzed ortho- or meta- C−H Olefination of Phenol Derivatives, J. Am. Chem. Soc., 2013, 135, 7567-7571. (16). Hu, B.-L.; Pi, S.-S.; Qian, P.-C.*; Li, J.-H.; Zhang, X.-G.*, Palladium-Catalyzed Iodine-Mediated Electrophilic Annulation of 2-(1-Alkynyl)biphenyls with Disulfides, J. Org. Chem., 2013, 78, 1300-1305. (15). Sun, L.-L.; Hu, B.-L.; Tang, R.-Y.; Deng, C.-L.; Zhang, X.-G.*, Copper-Catalyzed Tandem C-C/C-O Bond-Forming Reactions of ortho-Halo-β-chlorostyrenes with Ketones: Synthesis of 4-Trifluoromethyl- benzoxepines, Adv. Synth. Catal. 2013, 355, 377–382. (14). Wang, W.-Y.; Sun, L.-L.; Deng, C.-L.; Tang, R.-Y.; Zhang, X.-G.*, Palladium Catalyzed Tandem Carbocyclization/Suzuki Coupling Reaction of Trifluoromethyl-Containing Building Blocks Leading to 2-Trifluoromethylindenes, Synthesis, 2013, 45, 118-126. (13). Wasa, M.; Chan, K. S. L.; Zhang, X.-G., He, J.; Miura, M.; Yu, J.-Q.*, Ligand-Enabled Methylene C(sp3)−H Bond Activation with a Pd(II) Catalyst, J. Am. Chem. Soc., 2012, 134, 18570-18572. (12). Sun, L.-L.; Liao, Z.-Y.; Tang, R.-Y.; Deng, C.-L.; Zhang, X.-G.*, Palladium and Copper Co-catalyzed Tandem N-H/C-H Bond Functionalization: Synthesis of CF3-Containing Indolo- and Pyrrolo[2,1-a]isoquinolines, J. Org. Chem., 2012, 77, 2850-2856. (11). Shi, S.; Sun, L.-L.; Liao, Z.-Y.; Zhang, X.-G.*, Copper-Catalyzed Thiolation Cyclization of 1-Chloro-1,5-enynes with Sodium Hydrosulfide: Synthesis of CF3-Containing 1H-Isothiochromenes, Synthesis, 2012, 44, 966-972. (10). Sun, L.-L.; Deng, C.-L.; Tang, R.-Y.; Zhang, X.-G.*, CuI/TMEDA-Catalyzed Annulation of 2-Bromo Alkynylbenzenes with Na2S: Synthesis of Benzo[b]thiophenes, J. Org. Chem. 2011, 76, 7546–7550. Highlighted by Synfacts, 2011, 12, 1295. (9). Du, H.-A.; Tang, R.-Y.; Deng, C.-L.; Liu, Y.; Li, J.-H.*; Zhang, X.-G.*, Iron-Facilitated Iodine-Mediated Electrophilic Annulation of N,N-Dimethyl-2-alkynylanilines with Disulfides or Diselenides, Adv. Synth.Catal. 2011, 353, 2739–2748. (8). Fang, X.-L.; Tang, R.-Y.; Zhang, X.-G.*; Li, J.-H.*, FeF3/I2-Catalyzed Synthesis of 4-Chalcogen-Substituted Arylamines by Direct Thiolation of an Arene C–H Bond, Synthesis, 2011, 1099-1105. (7). Li, C.-L. Zhang, X.-G.*; Tang, R.-Y.; Zhong, P.; Li, J.-H.*, Copper-Catalyzed Thiolation Annulations of 1,4-Dihalides with Sulfides Leading to 2-Trifluoromethyl Benzothiophenes and Benzothiazoles, J. Org. Chem. 2010, 75, 7037–7040. (6). Dong, S.-X.; Zhang, X.-G.*; Liu, Q.; Tang, R.-Y.; Zhong, P.; Li, J.-H.*, Synthesis of 1-Substituted 2-(Trifluoromethyl)indoles via a Palladium-Catalyzed Double Amination Reaction, Synthesis, 2010, 1521-1525. (5). Li, C.-L.; Chen, M.-W.; Zhang, X.-G.*, Synthesis of N-aryl Trifluoromethylaryl-Ketoimines by Palladium-Catalyzed Suzuki Coupling Reaction of N-Aryltrifluoroacetimidoyl Chlorides with Arylboronic Acids, J. Fluorine Chem. 2010, 131, 856–860. (4). Guo, Y.-J.; Tang, R.-Y.; Li, J.-H.*; Zhong, P.; Zhang, X.-G.*, Palladium-Catalyzed Annulation of 2-(1-Alkynyl)benzenamines with Disulfides: Synthesis of 3-Sulfenylindoles, Adv. Synth. & Catal. 2009, 351, 2615-2618.(3). Du, H.-A.; Zhang, X.-G.*; Tang, R.-Y.; Li, J.-H.*, PdCl2-Promoted Electrophilic Annulation of 2-Alkynylphenol Derivatives with Disulfides or Diselenides in the Presence of Iodine, J. Org. Chem. 2009, 74, 7844-7848. (2). Chen, M.-W.; Zhang, X.-G.*; Zhong, P.; Hu, M.-L., Copper-Catalyzed Tandem C-N Bond Formation Reaction: Selective Synthesis of 2-(Trifluoromethyl)benzimidazoles, Synthesis, 2009, 1431-1436. (1). Zhang, X.-G.*; Chen, M.-W.; Zhong, P.*; Hu, M.-L., Regio- and Stereo-specific Preparation of (E)-1-Aryl-3,3,3-trifluoro-1-iodo-propenes and Their Palladium-Catalyzed Reaction with Terminal Alkynes, J. Fluorine Chem. 2008, 129, 335-342. |