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科学研究

祝贺刘妙昌和吴华悦老师指导研究生在ORGANIC LETTERS上发表学术论文

发布时间:2018-01-18    来源:    作者:    点击次    [点击关闭]

标题:Synergistic Photo-Copper-Catalyzed Hydroxylation of (Hetero)aryl Halides with Molecular Oxygen

AbstactPhotoredox-mediated copper-catalyzed hydroxylation of (hetero)aryl halides (including chlorides, bromides, and iodides) with O2 at room temperature has been developed. Preliminary mechanistic studies indicate no arylcopper intermediate and that aryl radicals are involved in this procedure. 18O-labeling experiments confirm the hydroxyl oxygen atom originated from molecular oxygen.

DOI: 10.1021/acs.orglett.7b03840

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