温州大学化学与材料工程学院

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科学研究

祝贺王舜和金辉乐老师指导研究生在Advanced Energy Materials上发表学术论文

发布时间:2018-01-26    来源:    作者:    点击次    [点击关闭]

标题:High Volumetric Capacitance, Ultralong Life Supercapacitors Enabled by Waxberry-Derived Hierarchical Porous Carbon Materials

AbstactSupercapacitors with fast charge/discharge rate and long cycling stability (>50 000 cycles) are attractive for energy storage and mobile power supply. In this paper, a facile strategy is developed to fabricate an Fe2O3/FeS-decorated N, S-codoped hierarchical porous carbon hybrid. Its microstructure and compositions can be readily controlled through adjusting the hydrothermal reaction between waxberry and iron sulfate. The constructed supercapacitors with the as-prepared carbon materials from this reaction are able to exhibit outstanding capacitive performance with a superfast charge/discharge rate (<1 s), ultralong cycle life (>50 000 cycles, 80 A g1), ultrahigh volumetric capacitance (1320.4 F cm3, 0.1 A g1), and high energy density (100.9 W h kg1, 21.9 W h L1). The outstanding performance makes it one of the best iomass-derived supercapacitors. The superior capacitive behavior is likely to rise from the N and S codoping on the surface/edge/skeleton of the carbon microspheres and nanosheet composites coupled with the fast redox reaction f Fe2O3/FeS. Overall, this research presents a new avenue for developing the ext generation of sustainable high-performance energy storage device..

DOI: 10.1002/aenm.201702695

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