温州大学化学与材料工程学院

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祝贺夏远志老师在Organic Chemistry Frontiers发表学术论文

发布时间:2018-09-11    来源:化学与材料工程学院    作者:    点击次    [点击关闭]

标题:Reaction of silylallenes with triplet molecular oxygen

 

AbstactA facile formal ene reaction of trisubstituted silylallenes with triplet molecular oxygen involving the cleavage of a HC(sp2) bond has been described. For this formal ene reaction, the silyl substituent was found to be critical to induce peroxide formation. DFT calculations clearly show the dramatic weakening of the allenic C(sp2)H bond by the α-silyl group

 

原文链接:

https://doi.org/10.1039/c8qo00390d