个人简介

上官之春，博士。2022年8月博士毕业于上海交通大学化学化工学院，同年8月入站中国科学院化学研究所从事博士后研究工作，出站后加入温州大学化学与材料工程学院从事教学科研工作。主要从事刺激响应型有机光电功能材料的设计合成及其应用。迄今为止，在Sci. Adv., J. Am. Chem. Soc., Macromolecules, Chem. Sci., Chin. Chem. Lett.等国内外主流期刊上发表论文二十余篇，其中第一或通讯作者9篇，参与编写专著1本。主持北京分子科学国家研究中心、浙江省自然科学基金、浙江省教育厅一般项目等多项科研项目。

工作经历

2025.5-至今，温州大学化学与材料工程学院，讲师

2022.8-2024.10，中国科学院化学研究所，博士后，合作导师：张德清 研究员

教育经历

2018.4-2022.8，上海交通大学化学化工学院，博士，导师：李涛 教授

2012.9-2015.7，上海师范大学化学与材料科学学院，硕士，导师：肖胜雄 教授

2007.9-2011.7，天津工业大学 学士

研究方向

刺激响应型有机光电功能材料的设计合成及其应用 

科研项目

1.      浙江省自然科学基金青年项目，LQN26B040009，在研，主持。

2.      浙江省教育厅一般项目，Y202558152，在研，主持。

3.      北京分子科学国家研究中心，博士后项目 2022BMS20093，已结题，主持。

代表性论文

专著：

1.      上官之春，张召阳，李涛，《碳中和关键问题与颠覆性技术》第十二章“分子光储能”，清华大学出版社，2022，ISBN: 9787302621096.

科研论文：

1.        Li H.^†, Shangguan Z.^†, Li T.*, Zhang Z.-Y., Ji D.*, Hu W., "Arylazopyrazole-Modulated Stable Dual-Mode Phototransistors", Sci. Adv., 2024, 10, eado2329. (^†Co-first author)

2.        Li H.^†, Garner M. H.^†, Shangguan Z.^†, Chen Y., Zheng Q., Su T. A., Neupane M., Liu T., Steigerwald M. L., Ng F., Nuckolls C., Xiao S.*, Solomon G. C.*, Venkataraman L.*, "Large Variations in the Single-Molecule Conductance of Cyclic and Bicyclic Silanes", J. Am. Chem. Soc., 2018, 140, 15080-15088. (^†Co-first author)

3.        Shangguan Z., Yin Z., Li C., Shang W., Chen L., Gao C., Xue X., Zhang X.-S., Zhang G., Zhang D.*, "Benzo[1,2-b:4,5-b']dithiophenedimides as an Electron-deficient Building Block for n-Type Polymer Semiconductors", Macromolecules, 2024, 57, 6540-6547.

4.        Shangguan Z., Sun W., Zhang Z.-Y., Fang D., Wang Z., Wu S., Deng C., Huang X., He Y., Wang R., Li T., Moth-Poulsen K.*, Li T.*, "A Rechargeable Molecular Solar Thermal System Below 0 ℃", Chem. Sci., 2022, 13, 6950-6958.

5.        Chen L.*, Huang H., Zhu Q., Zeng Y., Shangguan Z.*, Chen J., Wang X.*, Li C., Zhang G., Fu H., Zhang D., "Cocrystal Engineering for Constructing Emissive Ambipolar Semiconductor Based on Diphenylanthracene and Diperfluorophenylanthracene", Chin. Chem. Lett., 2026, 37, 111613.

6.        Shangguan Z., Li C., Chen L., Xue X., Chen C., Zhang X., Li Y., Zhang X., Zhang G., Zhang D.*, "Enhancing the Stretchability of Polymer Semiconductors by Incorporating Di-2-thienylsulfide as the p−π Conjugation Unit into the Backbones", Polym. Sci. Technol., 2025, 1, 351-358.

7.        Li H.^†, Garner M. H.^†, Shangguan Z.^†, Zheng Q., Su T. A., Neupane M., Li P., Velian A., Steigerwald M. L., Xiao S.*, Nuckolls C.*, Solomon G. C.*, Venkataraman L.*, "Conformations of Cyclopentasilane Stereoisomers Control Molecular Junction Conductance", Chem. Sci., 2016, 7, 5657-5662. (^†Co-first author)

8.        Huang X.^†, Shangguan Z.^†, Zhang Z.-Y., Yu C., He Y., Fang D., Sun W., Li Y., Yuan C., Wu S.*, Li T.*, "Visible-Light-Induced Reversible Photochemical Crystal–Liquid Transitions of Azo-Switches for Smart and Robust Adhesives", Chem. Mater., 2022, 34, 2636-2644. (Co-first author)

9.        Shangguan Z., Yu C., Li C., Huang X., Mai Y.*, Li T.*, "Azobenzene-Functionalized Graphene Nanoribbons: Bottom-Up Synthesis, Photoisomerization Behaviour and Self-Assembled Structures", J. Mater. Chem. C, 2020, 8, 10837-10843.

10.    Hu Y., Gao X.*, Ma J., Shangguan Z., Chen L., Zhang G.*, Zhang X., Li C., Li Y., Zhang D.*, "New AIE Emitters from the Unexpected Boron Tribromide/Boron Trichloride‐mediated Cyclization Reaction and Application for Fluorescence Imaging of Lipid Droplets", Aggregate, 2025, 6, e735.

11.    Shu Y., Huang J., Yang J., Shangguan Z., Ma J., Li C., Zhang G., Peng Q., Zhang X.*, Fan Q., Wang B.*, Zhang D*. "Heptene end-capped Thiele hydrocarbons with tunable configuration and emission and on-surface transformation via annulation", Chem. Commun., 2025, 61, 3994–3997.

12.    Chen L.*, Shangguan Z., Li M., Zhang G., Wang C., Zhang D., "High-Performance Vinyl-Flanked Diketopyrrolopyrrole–Selenophene Polymer Semiconductors with Branched, Linear and Cyclic Alkyl Side Chains", J. Mater. Chem. C, 2024, 12, 17050-17055.

13.    Xue X., Li C.*, Shangguan Z., Gao C., Chen C., Liao J., Zhang X.-S., Zhang G., Zhang D.*, "Intrinsically Stretchable and Healable Polymer Semiconductors", Adv. Sci., 2024, 11, 2305800.

14.    Ma Z., Qin L., Shangguan Z., Shu Y., Ma J., Liang Q., Li C., Zhang G., Zhang X.-S.*, Duan Z.*, Zhang D., "Synthesis of Dibenzoazulene Derivatives via Pd‐Catalyzed (3 + 2) Alkyne Annulation of Dibenzosuberenone", ChemCatChem, 2024, 16, e202401310.

15.    Shang W., Meng W., Chen L., Shangguan Z., Huang Y., Zhang X.-S., Li C., Bai S., Zhang G., Zhang D.*, "Novel Dissymmetric Formal Quinoidal Molecules End‐Capped by Dicyanomethylene and Triphenylphosphonium", Angew. Chem. Int. Ed., 2024, 63, e202412704.

16.    Xue X., Li C.*, Zhou Q., Yu X., Gao C., Chen C., Liao J., Shangguan Z., Zhang X.-S., Zhang G., Zhang D.*, "Conjugated Polymer-Based Photo-Crosslinker for Efficient Photo-Patterning of Polymer Semiconductors", Adv. Mater. 2024, 36, 2407305.

17.    Gao C., Li C.*, Yang Y., Jiang Z., Xue X., Chen C, Liao J., Shangguan Z., Wu C., Zhang X.-S., Jia D., Zhang F., Liu G., Zhang G., Zhang D.* "Nonhalogenated Solvent Processable and High‐Density Photopatternable Polymer Semiconductors Enabled by Incorporating Hydroxyl Groups in the Side Chains", Adv. Mater. 2024, 36, 2309256.

18.    Sun W., Shangguan Z., Zhang X., Dang T., Zhang Z.-Y.*, Li T.*, "Solar Efficiency of Azo-Photoswitches for Energy Conversion: A Comprehensive Assessment", ChemSusChem, 2023, 16, e202300582.

19.    He Y., Shangguan Z., Zhang Z.-Y.*, Xie M., Yu C., Li T.*, "Azobispyrazole Family as Photoswitches Combining (Near-) Quantitative Bidirectional Isomerization and Widely Tunable Thermal Half-Lives from Hours to Years", Angew. Chem. Int. Ed., 2021, 60, 16539-16546.

20.    Fang D., Zhang Z.-Y.*, Shangguan Z., He Y., Yu C., Li T.*, "(Hetero)arylazo-1,2,3-triazoles: "Clicked" Photoswitches for Versatile Functionalization and Electronic Decoupling", J. Am. Chem. Soc., 2021, 143, 14502-14510.

21.    Garner M. H.^†, Li H.^†, Neupane M.^†, Zou Q., Liu T., Su T. A., Shangguan Z., Paley D. W., Ng F., Xiao S., Nuckolls C.*, Venkataraman L.*, Solomon G. C.*, "Permethylation Introduces Destructive Quantum Interference in Saturated Silanes", J. Am. Chem. Soc., 2019, 141, 15471-15476.

22.    Wang Q., Ma L., Liu Z., Zhang X., Zhang Z., Shangguan Z., Huang X., Liu Y., Lv J.*, Zhang H., Chi L., Li T.*, "Triazatriangulene Platform for Self-Assembled Monolayers of Free-Standing Diarylethene", Sci. China Mater., 2018, 61, 1345-1350.

23.    Garner M. H.^†, Li H.^†, Chen Y.^†, Su T. A., Shangguan Z., Paley D. W., Liu T., Ng F., Li H., Xiao S.*, Nuckolls C.*, Venkataraman L.*, Solomon G. C.*, "Comprehensive Suppression of Single-Molecule Conductance Using Destructive σ-Interference", Nature, 2018, 558, 415-419.